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Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF, Thermo Scientific Chemicals

£133.00 - £455.00

Chemical Identifiers

CAS 807329-97-1
Molecular Formula C3H7Cl2LiMg
Molecular Weight (g/mol) 145.23
MDL Number MFCD07784514
InChI Key CWTUREABAILGIK-UHFFFAOYSA-L
Synonym turbo grignard, iprmgcl licl, i-prmgcl licl, i-prmgcl.licl, isopropylmagnesiumchloride licl, isopropylmagnesium chloride licl, isopropyl magnesium chloride licl, cwtureabailgik-uhfffaoysa-l, isopropylmagnesium lithium chloride, isopropyl magnesium chloride li-cl
IUPAC Name lithium(1+) chloro(propan-2-yl)magnesium chloride
SMILES [Li+].[Cl-].CC(C)[Mg]Cl
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H51156.AE
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H51156.AP
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Description

Description

Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.

Solubility
Miscible with ethers and amines.

Notes
Air and moisture sensitive. Incompatible with oxidizing agents and water.
Specifications

Chemical Identifiers

807329-97-1
145.23
CWTUREABAILGIK-UHFFFAOYSA-L
lithium(1+) chloro(propan-2-yl)magnesium chloride
C3H7Cl2LiMg
MFCD07784514
turbo grignard, iprmgcl licl, i-prmgcl licl, i-prmgcl.licl, isopropylmagnesiumchloride licl, isopropylmagnesium chloride licl, isopropyl magnesium chloride licl, cwtureabailgik-uhfffaoysa-l, isopropylmagnesium lithium chloride, isopropyl magnesium chloride li-cl
[Li+].[Cl-].CC(C)[Mg]Cl

Specifications

807329-97-1
−17°C (1.4°F)
(CH3)2CHMgCl·LiCl
UN3399
turbo grignard, iprmgcl licl, i-prmgcl licl, i-prmgcl.licl, isopropylmagnesiumchloride licl, isopropylmagnesium chloride licl, isopropyl magnesium chloride licl, cwtureabailgik-uhfffaoysa-l, isopropylmagnesium lithium chloride, isopropyl magnesium chloride li-cl
CWTUREABAILGIK-UHFFFAOYSA-L
lithium(1+) chloro(propan-2-yl)magnesium chloride
145.24
Isopropylmagnesium chloride - LiCl complex
0.951
C3H7Cl2LiMg
MFCD07784514
Air and moisture sensitive
Miscible with ethers and amines.
[Li+].[Cl-].CC(C)[Mg]Cl
145.23
1M in MeTHF
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Safety and Handling

Safety and Handling

GHS H Statement
H225-H261-H314-H318
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Causes serious eye damage.

P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P335+P334-P363-P370+P378q-P501c

H225-H260-H302-H314-H335

missing translation for 'dotInformation' : Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE

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Recommended Storage : Ambient temperatures

SDS
Documents

Documents

Product Certifications

RUO – Research Use Only