Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF, Thermo Scientific Chemicals

Product Code	Brand	Quantity
15449205	Thermo Scientific Alfa Aesar H51156.AE	100 mL
15459205	Thermo Scientific Alfa Aesar H51156.AP	500 mL

Description

Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.

Solubility
Miscible with ethers and amines.

Notes
Air and moisture sensitive. Incompatible with oxidizing agents and water.

Chemical Identifiers

• CAS: 807329-97-1
• Molecular Weight (g/mol): 145.23
• InChI Key: CWTUREABAILGIK-UHFFFAOYSA-L
• IUPAC Name: lithium(1+) chloro(propan-2-yl)magnesium chloride

• Molecular Formula: C3H7Cl2LiMg
• MDL Number: MFCD07784514
• Synonym: turbo grignard, iprmgcl licl, i-prmgcl licl, i-prmgcl.licl, isopropylmagnesiumchloride licl, isopropylmagnesium chloride licl, isopropyl magnesium chloride licl, cwtureabailgik-uhfffaoysa-l, isopropylmagnesium lithium chloride, isopropyl magnesium chloride li-cl
• SMILES: [Li+].[Cl-].CC(C)[Mg]Cl

Specifications

• CAS: 807329-97-1
• Flash Point: −17°C (1.4°F)
• Linear Formula: (CH₃)₂CHMgCl·LiCl
• UN Number: UN3399
• Synonym: turbo grignard, iprmgcl licl, i-prmgcl licl, i-prmgcl.licl, isopropylmagnesiumchloride licl, isopropylmagnesium chloride licl, isopropyl magnesium chloride licl, cwtureabailgik-uhfffaoysa-l, isopropylmagnesium lithium chloride, isopropyl magnesium chloride li-cl
• InChI Key: CWTUREABAILGIK-UHFFFAOYSA-L
• IUPAC Name: lithium(1+) chloro(propan-2-yl)magnesium chloride
• Formula Weight: 145.24
• Chemical Name or Material: Isopropylmagnesium chloride - LiCl complex

• Density: 0.951
• Molecular Formula: C3H7Cl2LiMg
• MDL Number: MFCD07784514
• Sensitivity: Air and moisture sensitive
• Solubility Information: Miscible with ethers and amines.
• SMILES: [Li+].[Cl-].CC(C)[Mg]Cl
• Molecular Weight (g/mol): 145.23
• Concentration or Composition (by Analyte or Components): 1M in MeTHF

Safety and Handling

GHS H Statement
H225-H261-H314-H318
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Causes serious eye damage.

P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P335+P334-P363-P370+P378q-P501c

H225-H260-H302-H314-H335

missing translation for 'dotInformation' : Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE

missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures

RUO – Research Use Only