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Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF

Product Code. 15459205
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Product Code. 15459205 Supplier Thermo Scientific Alfa Aesar Supplier No. H51156.AP
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Description

CAS: 807329-97-1 | C3H7Cl2LiMg | 145.23 g/mol

Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.

Solubility
Miscible with ethers and amines.

Notes
Air and moisture sensitive. Incompatible with oxidizing agents and water.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 807329-97-1
Molecular Formula C3H7Cl2LiMg
Molecular Weight (g/mol) 145.23
MDL Number MFCD07784514
InChI Key CWTUREABAILGIK-UHFFFAOYSA-L
Synonym turbo grignard, iprmgcl licl, i-prmgcl licl, i-prmgcl.licl, isopropylmagnesiumchloride licl, isopropylmagnesium chloride licl, isopropyl magnesium chloride licl, cwtureabailgik-uhfffaoysa-l, isopropylmagnesium lithium chloride, isopropyl magnesium chloride li-cl
IUPAC Name lithium(1+) chloro(propan-2-yl)magnesium chloride
SMILES [Li+].[Cl-].CC(C)[Mg]Cl

Specifications

Density 0.951
Flash Point −17°C (1.4°F)
Linear Formula (CH3)2CHMgCl·LiCl
Quantity 500 mL
UN Number UN3399
Sensitivity Air and moisture sensitive
Solubility Information Miscible with ethers and amines.
Formula Weight 145.24
Concentration or Composition (by Analyte or Components) 1M in MeTHF
Chemical Name or Material Isopropylmagnesium chloride - LiCl complex

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