Triisobutylaluminium, 1.1M solution in toluene, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10178692	Thermo Scientific Acros 185421000	100 mL	AcroSeal™ Glass bottle
10301753	Thermo Scientific Acros 185428000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Lewis acid

Chemical Identifiers

• CAS: 100-99-2, 108-88-3
• Molecular Weight (g/mol): 198.33
• InChI Key: MCULRUJILOGHCJ-UHFFFAOYSA-N
• PubChem CID: 16682931
• SMILES: CC(C)C[Al](CC(C)C)CC(C)C

• Molecular Formula: C12H27Al
• MDL Number: MFCD00008929
• Synonym: triisobutylaluminum, triisobutylaluminium, aluminum, tris 2-methylpropyl, tibal, triisobutylalane, triisobutyl aluminum, aluminum, triisobutyl, tris isobutyl alane, tris isobutyl aluminum, unii-09p2thv2x4
• IUPAC Name: tris(2-methylpropyl)alumane

Specifications

• Color: Colorless to Yellow
• Molecular Formula: C12H27Al
• MDL Number: MFCD00008929
• Density: 0.8400g/mL
• Synonym: triisobutylaluminum, triisobutylaluminium, aluminum, tris 2-methylpropyl, tibal, triisobutylalane, triisobutyl aluminum, aluminum, triisobutyl, tris isobutyl alane, tris isobutyl aluminum, unii-09p2thv2x4
• InChI Key: MCULRUJILOGHCJ-UHFFFAOYSA-N
• IUPAC Name: tris(2-methylpropyl)alumane
• PubChem CID: 16682931
• Percent Purity: 24.5 to 25.5% (on Al basis)
• Flash Point: 4°C
• Chemical Name or Material: Triisobutylaluminium, 1.1M Solution in Toluene

• CAS: 100-99-2, 108-88-3
• Linear Formula: [(CH₃)₂CHCH₂]₃Al
• Fieser: 09,486
• Merck Index: 10, 316
• Solubility Information: Solubility in water: reacts. Other solubilities: miscible with aromatic and aliphatic hydrocarbons
• SMILES: CC(C)C[Al](CC(C)C)CC(C)C
• Molecular Weight (g/mol): 198.33
• Formula Weight: 198.33
• Specific Gravity: 0.84
• Physical Form: Solution

Safety and Handling

GHS H Statement
May be fatal if swallowed and enters airways. Causes severe skin burns and eye damage. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. Suspected of damaging the unborn child. Highly flammable liquid and vapor. In contact with water releases flammable gases which may ignite spontaneously. Reacts violently with water.

GHS P Statement
IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Use personal protective equipment as required. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do not breathe dust/fume/gas/mist/vapors/spray. IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. Do NOT induce vomiting. Store in a dry place. Store in a closed container.

Danger

Product Identifier

• Triisobutylaluminium, solution in toluene

Signal Word

• Danger

Hazard Category

• Aspiration toxicity Category 1
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Reproductive toxicity Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity after repeated exposure Category 2
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H304-May be fatal if swallowed and enters airways.
• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H361d-Suspected of damaging the unborn child.
• H373-May cause damage to organs.
• H336-May cause drowsiness or dizziness.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.

Precautionary Statement

• P260-Do not breathe dust/fume/gas/mist/vapours/spray.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.
• P331-Do NOT induce vomiting.
• P402+P404-Store in a dry place. Store in a closed container.

RUO – Research Use Only