Benzyl (triphenylphosphoranylidene)acetate, 97%, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10077002	Thermo Scientific Acros 377220050	5 g	Glass bottle
10766383	Thermo Scientific Acros 377220250	25 g	Glass bottle
10176943	Thermo Scientific Acros 377221000	100 g	Glass bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

for C-C Bond Formation (Olefination)

Chemical Identifiers

• CAS: 15097-38-8
• Molecular Weight (g/mol): 410.45
• InChI Key: INKMLGJBBDRIQR-UHFFFAOYSA-N
• PubChem CID: 3862746
• SMILES: O=C(OCC1=CC=CC=C1)C=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1

• Molecular Formula: C27H23O2P
• MDL Number: MFCD00191787
• Synonym: benzyl 2-triphenylphosphoranylidene acetate, benzyl triphenylphosphoranylidene acetate, benzyl triphenylphosphoranylidene-acetate, benzyl 2-triphenyl-??-phosphanylidene acetate, acetic acid, triphenylphosphoranylidene-, phenylmethyl ester, phenylmethyl 2-triphenylylidene acetate, benzyl 2-triphenyl, acmc-20ah9g, ksc526q3l
• IUPAC Name: benzyl 2-(triphenyl-$l^{5}-phosphanylidene)acetate

Specifications

• CAS: 15097-38-8
• CAS Max %: 100.0
• Color: White
• Assay Percent Range: 96% min. (HPLC)
• Linear Formula: (C₆H₅)₃P=CHCOOCH₂C₆H₅
• Synonym: benzyl 2-triphenylphosphoranylidene acetate, benzyl triphenylphosphoranylidene acetate, benzyl triphenylphosphoranylidene-acetate, benzyl 2-triphenyl-??-phosphanylidene acetate, acetic acid, triphenylphosphoranylidene-, phenylmethyl ester, phenylmethyl 2-triphenylylidene acetate, benzyl 2-triphenyl, acmc-20ah9g, ksc526q3l
• SMILES: O=C(OCC1=CC=CC=C1)C=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
• Molecular Weight (g/mol): 410.45
• Formula Weight: 410.45
• Physical Form: Powder

• CAS Min %: 96.0
• Melting Point: 120.0°C to 127.0°C
• Infrared Spectrum: Authentic
• Molecular Formula: C27H23O2P
• MDL Number: MFCD00191787
• InChI Key: INKMLGJBBDRIQR-UHFFFAOYSA-N
• IUPAC Name: benzyl 2-(triphenyl-$l^{5}-phosphanylidene)acetate
• PubChem CID: 3862746
• Percent Purity: 97%
• Chemical Name or Material: Benzyl (triphenylphosphoranylidene)acetate

Safety and Handling

GHS H Statement:
Harmful if inhaled.
May cause respiratory irritation.
Causes skin irritation.
Causes serious eye irritation.
Harmful if swallowed.
Harmful in contact with skin.

GHS P Statement:
Wear protective gloves/protective clothing/eye protection/face protection.
IF ON SKIN: Wash with plenty of soap and water.
Avoid breathing dust/fume/gas/mist/vapors/spray.
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

WARNING: The information provided on this web site was developed in compliance with European Union (EU) regulations and is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling and use. It is not to be considered as either a warranty or quality specification.

GHS Signal Word: Warning

Product Identifier

• Benzyl (triphenylphosphoranylidene)acetate

Signal Word

• Warning

Hazard Category

• Acute toxicity Category 4
• Serious eye damage/eye irritation Category 2
• Skin corrosion/irritation Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H315-Causes skin irritation.
• H319-Causes serious eye irritation.
• H335-May cause respiratory irritation.
• H312-Harmful in contact with skin.
• H332-Harmful if inhaled.
• H302-Harmful if swallowed.

Precautionary Statement

• P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P312-IF SWALLOWED: Call a POISON CENTER or doctor/physician/ if you feel unwell.
• P302+P352-IF ON SKIN: Wash with plenty of water/.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

RUO – Research Use Only