4-Methoxyphenylmagnesium bromide, 1M solution in THF, AcroSeal™, ACROS Organics™

Brand:  Acros Organics 377421000

Product Code. 10022442

Chemical Identifiers

• CAS: 13139-86-1
• Molecular Weight (g/mol): 211.34
• InChI Key: RBWRWAUAVRMBAC-UHFFFAOYSA-M
• PubChem CID: 2734898
• SMILES: COC1=CC=[C-]C=C1.[Mg+2].[Br-]

• Molecular Formula: C₇H₇BrMgO
• MDL Number: MFCD00013515
• Synonym: 4-methoxyphenylmagnesium bromide, grignard reagent, 4-methoxyphenylmagnesium bromide solution, bromo 4-methoxyphenyl magnesium, p-methoxyphenylmagnesium bromide, 4-methoxyphenyl magnesium bromide, 4-methoxyphenymagnesium bromide, 4-methoxy phenylmagnesiumbromide, p-methoxyphenyl magnesium bromide, p-methoxyphenyl-magnesium bromide, 4-methoxy-phenyl-magnesiumbromide
• IUPAC Name: magnesium;methoxybenzene;bromide

Specifications

• Chemical Name or Material: 4-Methoxyphenylmagnesium bromide
• Flash Point: −21°C
• Specific Gravity: 1
• Quantity: 100mL
• CAS Min %: 74.64
• Molecular Formula: C₇H₇BrMgO
• MDL Number: MFCD00013515
• Solubility Information: Solubility in water: vigorous reaction
• SMILES: COC1=CC=[C-]C=C1.[Mg+2].[Br-]
• Molecular Weight (g/mol): 211.34
• Formula Weight: 211.34

• Density: 1.0000g/mL
• Packaging: AcroSeal™ Glass bottle
• Color: Yellow to Brown
• CAS: 13139-86-1,109-99-9
• CAS Max %: 80.98
• Linear Formula: CH₃O(C₆H₄)MgBr
• Synonym: 4-methoxyphenylmagnesium bromide, grignard reagent, 4-methoxyphenylmagnesium bromide solution, bromo 4-methoxyphenyl magnesium, p-methoxyphenylmagnesium bromide, 4-methoxyphenyl magnesium bromide, 4-methoxyphenymagnesium bromide, 4-methoxy phenylmagnesiumbromide, p-methoxyphenyl magnesium bromide, p-methoxyphenyl-magnesium bromide, 4-methoxy-phenyl-magnesiumbromide
• InChI Key: RBWRWAUAVRMBAC-UHFFFAOYSA-M
• IUPAC Name: magnesium;methoxybenzene;bromide
• PubChem CID: 2734898
• Physical Form: Liquid

Safety and Handling

Product Identifier

• 4-Methoxyphenylmagnesium bromide, 1M solution in THF

Signal Word

• Danger

Hazard Category

• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3

Hazard Statement

• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H351-Suspected of causing cancer.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.