1,1'-Bis(diphenylphosphino)ferrocene, 97%


Overview
Brand: Alfa Aesar

Manufacturer Part Number: B21166-03

1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE, 97%,1G

UNSPSC: 12141721

Code: NEW

Additional Details:
Additional Details: CAS Number: 12150-46-8 Weight: 0.01000kg


Quantity 1g

Product Code. 11454657

Quantity Price
1 £ 22.05 / 1g
Estimated Shipment date
from Supplier 07-12-2016
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Description and Specification

Chemical Identifiers

Chemical Name or Material 1, 1'-Bis(diphenylphosphino)ferrocene
CAS 12150-46-8
Molecular Formula C34H28FeP2
Formula Weight 554.40g/mol
MDL Number MFCD00001422

Specification

Quantity 1g
Chemical Name or Material 1, 1'-Bis(diphenylphosphino)ferrocene
CAS 12150-46-8
Assay 97%
Assay Percent Range 0.97
Molecular Formula C34H28FeP2
Formula Weight 554.40g/mol
MDL Number MFCD00001422
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for se
Storage Note 1 Air Sensitive
Recommended Storage 2° to 8°C

Applications
1,1′-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

Solubility
Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.

Notes
Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.

Safety and Handling

Warning

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for se

Air Sensitive

2° to 8°C