Alfa Aesar™ Trifluoromethanesulfonic anhydride, 98%


Overview
Brand: Alfa Aesar™

Manufacturer Part Number: A11767-18

TRIFLUOROMETHANESULFONIC ANHYDRIDE, 98+%50G

UNSPSC: 12352106

Code: NEW

Additional Details:
Additional Details: CAS Number: 358-23-6 Weight: 0.01000kg


Quantity 50g

Product Code. 11453910

Quantity Price
1 £ 158.36 / 50g
Estimated Shipment date
from Supplier 14-12-2016
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Description and Specification

Chemical Identifiers

Chemical Name or Material Trifluoromethanesulfonic anhydride
CAS 358-23-6
Molecular Formula C2F6O5S2
Linear Formula (CF3SO2)2O
Formula Weight 282.13g/mol
MDL Number MFCD00000408
UN Number UN3265
Beilstein 1813600
Synonym Triflic anhydride

Specification

Boiling Point 81° to 83°C
Melting Point −80°C
Quantity 50g
Chemical Name or Material Trifluoromethanesulfonic anhydride
CAS 358-23-6
Assay 98%
Molecular Formula C2F6O5S2
Linear Formula (CF3SO2)2O
Formula Weight 282.13g/mol
MDL Number MFCD00000408
UN Number UN3265
Beilstein 1813600
Synonym Triflic anhydride
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
Health Hazard 3 GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF SWALLOWED: Rinse mouth.
Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
DOT Information Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
RTECS Number PB2772000
TSCA TSCA

Applications
Trifluoromethanesulfonic anhydride is used to convert phenols and imine into triflic ester and NTf group. It is a strong electrophile used for the introduction of triflyl group in chemical synthesis. It serves as a reagent in the preparation of alkyl and vinyl triflates, and for the stereoselective synthesis of mannosazide methyl uronate donors. It acts as a catalyst for glycosylation with anomeric hydroxy sugars to prepare polysaccharides.

Solubility
Miscible with dichloromethane. Immiscible with hydrocarbons.

Notes
Moisture sensitive. Incompatible with water, strong bases, strong oxidizing agents, acids and alcohols.

Safety and Handling

Danger

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF SWALLOWED: Rinse mouth.
Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.