Alfa Aesar™ Trichloroacetonitrile, 98%


Overview
Brand: Alfa Aesar™

Manufacturer Part Number: A10565.0B

UNSPSC: 12352101

Code: NEW

Additional Details:
Additional Details: CAS Number: 545-06-2 Weight: 0.01000kg


Quantity 1000g

Product Code. 11443214

Quantity Price
1 £ 245.81 / 1000g
Estimated Shipment date
from Supplier 10-04-2017
Add to basket


Description and Specification

Chemical Identifiers

Chemical Name or Material Trichloroacetonitrile
CAS 545-06-2
Molecular Formula C2Cl3N
Linear Formula Cl3CCN
Formula Weight 144.39
MDL Number MFCD00001842
UN Number UN3276
Beilstein 605572
Merck Index 14,9628

Specification

Formula Weight 144.39
Assay Percent Range 98%
Health Hazard 3 GHS P Statement
P261-P280-P301+P310-P361-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
Remove/Take off immediately all contaminated clothing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Assay 98%
Melting Point −44°C
UN Number UN3276
RTECS Number AM2450000
CAS 545-06-2
Molecular Formula C2Cl3N
TSCA TSCA
Quantity 1000g
Health Hazard 1 Danger
Chemical Name or Material Trichloroacetonitrile
Linear Formula Cl3CCN
Health Hazard 2 GHS H Statement
H301-H311-H331
Toxic if swallowed.
Toxic in contact with skin.
Toxic if inhaled.
Boiling Point 85° to 86°C
MDL Number MFCD00001842
DOT Information Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: NITRILES, LIQUID, TOXIC, N.O.S.
Beilstein 605572
Merck Index 14,9628

Applications
Trichloroacetonitrile is involved as a reagent in Overman rearrangement, which is used to prepare alylic amines from allylic alcohols. It is also used to prepare bistrichloroacetimidates from diols leading to dihyrooxazines through acid catalyzed cyclization. Further, it is utilized in the synthesis of trichloroacetimidates by 1,8-Diazobicyclo[5.4.0]undec-7-ene (DBU) catalyzed addition of allylic alcohols. It finds application in the study of the methoxy methyl (MOM) catalyzed aza-Claisen rearrangement.

Solubility
Miscible with most organic solvents. Immiscible with water.

Notes
Incompatible with strong acids, strong bases, strong oxidizing agents and strong reducing agents.

Documentation

Technical documents

Safety and Handling

Danger

GHS H Statement
H301-H311-H331
Toxic if swallowed.
Toxic in contact with skin.
Toxic if inhaled.

GHS P Statement
P261-P280-P301+P310-P361-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
Remove/Take off immediately all contaminated clothing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.