Alfa Aesar™ Tetra-n-butylammonium fluoride, 1M soln. in THF


Overview
Brand: Alfa Aesar™

Manufacturer Part Number: A10588-AE

TETRA-N-BUTYLAMMONIUM FLUORIDE 1M SOL IN THF,100ML

UNSPSC: 12352101

Code: NEW

Additional Details:
Additional Details: CAS Number: 429-41-4 Weight: 0.01000kg


Quantity 100mL

Product Code. 11433254

Quantity Price
1 £ 40.49 / 100mL
Estimated Shipment date
from Supplier 09-12-2016
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Description and Specification

Chemical Identifiers

Chemical Name or Material Tetra-n-butylammonium fluoride
CAS 429-41-4
Molecular Formula C16H36FN
Linear Formula [CH3(CH2)3]4NF
Formula Weight 261.47g/mol
MDL Number MFCD00011747
UN Number UN2924
Beilstein 3570522
Synonym TBAF

Specification

Flash Point −17°C (1°F)
Concentration 1M soln. in THF
Quantity 100mL
Chemical Name or Material Tetra-n-butylammonium fluoride
CAS 429-41-4
Molecular Formula C16H36FN
Linear Formula [CH3(CH2)3]4NF
Formula Weight 261.47g/mol
MDL Number MFCD00011747
UN Number UN2924
Beilstein 3570522
Synonym TBAF
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H225-H314-H351-H302-H335
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
Suspected of causing cancer.
Harmful if swallowed.
May cause respiratory irritation.
Health Hazard 3 GHS P Statement
P210-P260-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces.
- No smoking.
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
DOT Information Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.
TSCA TSCA

Applications
Tetra-n-butylammonium fluoride, 1M soln. in THF is used as a reactant for the preparation of triple monoamine reuptake inhibitors as a new generation of antidepressants, oligoribonucleotides with phosphonate-modified linkages, conjugated dienoic acid esters using Suzuki coupling reactions and polyacetylenic glucosides. It plays an important role in aryl alkyl alcohols through Nozaki-Hiyama allylation catalyzed by chiral bipyridyldiol ligands and chromium trichloride. It is also used as a catalyst for the silylation reactions. In addition, it is used as a source of fluoride ion in organic solvents as well as for the deprotection of silyl ether groups.

Solubility
Miscible with terahydrofuran, acetonitrile, dimethyl sulfoxide and organic solvents.

Notes
Store in a cool place. Hygroscopic. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents and oxygen.

Safety and Handling

Danger

GHS H Statement
H225-H314-H351-H302-H335
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
Suspected of causing cancer.
Harmful if swallowed.
May cause respiratory irritation.

GHS P Statement
P210-P260-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces.
- No smoking.
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.