tert-Butyl nitrite, tech. 90%

Code produit	Quantity	unitSize
11392897	100 g	100g
11382897	25 g	25g

Code produit 11392897 Fournisseur Thermo Scientific Alfa Aesar Code fournisseur L16135.22

Description

CAS: 540-80-7 | C4H9NO2 | 103.121 g/mol

tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.

Solubility
Miscible with diethyl ether, chloroform, alcohol and carbon disulfide. Slightly miscible with water. Immiscible with glycerol.

Notes
Light sensitive. Store in cool place. Incompatible with strong reducing agents, powdered metals and strong acids.

Spécification

Identifiants chimiques

• CAS: 540-80-7
• Molecular Formula: C4H9NO2
• Molecular Weight (g/mol): 103.121
• MDL Number: MFCD00002055
• InChI Key: IOGXOCVLYRDXLW-UHFFFAOYSA-N
• Synonym: t-butyl nitrite, 1,1-dimethylethyl nitrite, tert-butylnitrite, nitrous acid, 1,1-dimethylethyl ester, unii-4780h7u8lu, ccris 2098, alpha,alpha-dimethylethyl nitrite, nitrous acid, t-butyl ester, 2-methyl-2-propylnitrit, ch3 3cono
• PubChem CID: 10906
• IUPAC Name: tert-butyl nitrite
• SMILES: CC(C)(C)ON=O

• Density: 0.867
• Boiling Point: 61°C to 63°C
• Flash Point: −23°C (−9°F)
• Odor: Sweet
• Refractive Index: 1.369
• Quantity: 100 g
• UN Number: UN2351
• Beilstein: 1209339
• Merck Index: 14,1583
• Solubility Information: Miscible with diethyl ether,chloroform,alcohol and carbon disulfide. Slightly miscible with water. Immiscible with glycerol.
• Formula Weight: 103.12
• Percent Purity: 90%
• Grade: Technical
• Chemical Name or Material: tert-Butyl nitrite

Sécurité et traitement

Identifiant produit

• tert-Butyl nitrite

Mention d'avertissement

• Danger

Catégorie de danger

• Acute toxicity Category 4
• Flammable liquid Category 2

Mention de danger

• H225-Highly flammable liquid and vapour.
• H302-Harmful if swallowed.
• H332-Harmful if inhaled.

Conseils de prudence

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P312-Call a POISON CENTER/doctor/if you feel unwell.

Informations supplémentaires

• MIXTURE LIST-Contain: tert-Butyl nitrite

RUO – Research Use Only