tert-Butyl nitrite, tech. 90%

Produktkod. 11382897

Brand: Thermo Scientific Alfa Aesar L16135.14

Beskrivning

CAS: 540-80-7 | C4H9NO2 | 103.121 g/mol

tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.

Solubility
Miscible with diethyl ether, chloroform, alcohol and carbon disulfide. Slightly miscible with water. Immiscible with glycerol.

Notes
Light sensitive. Store in cool place. Incompatible with strong reducing agents, powdered metals and strong acids.

Specifikationer

Kemiska identifierare

• CAS: 540-80-7
• Molecular Formula: C4H9NO2
• Molecular Weight (g/mol): 103.121
• MDL Number: MFCD00002055
• InChI Key: IOGXOCVLYRDXLW-UHFFFAOYSA-N
• Synonym: t-butyl nitrite, 1,1-dimethylethyl nitrite, tert-butylnitrite, nitrous acid, 1,1-dimethylethyl ester, unii-4780h7u8lu, ccris 2098, alpha,alpha-dimethylethyl nitrite, nitrous acid, t-butyl ester, 2-methyl-2-propylnitrit, ch3 3cono
• PubChem CID: 10906
• IUPAC Name: tert-butyl nitrite
• SMILES: CC(C)(C)ON=O

• Density: 0.867
• Boiling Point: 61°C to 63°C
• Flash Point: −23°C (−9°F)
• Odor: Sweet
• Refractive Index: 1.369
• Quantity: 25 g
• UN Number: UN2351
• Beilstein: 1209339
• Merck Index: 14,1583
• Solubility Information: Miscible with diethyl ether,chloroform,alcohol and carbon disulfide. Slightly miscible with water. Immiscible with glycerol.
• Formula Weight: 103.12
• Percent Purity: 90%
• Grade: Technical
• Chemical Name or Material: tert-Butyl nitrite

Säkerhet och hantering

Produktbeteckning

• tert-Butyl nitrite

Signalord

• Danger

Riskkategorier

• Acute toxicity Category 4
• Flammable liquid Category 2

Faroangivelser

• H225-Highly flammable liquid and vapour.
• H332-Harmful if inhaled.

Skyddsangivelse

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P312-Call a POISON CENTER/doctor/if you feel unwell.

Kompletterande information

• MIXTURE LIST-Contains : tert-Butyl nitrite

SDS

RUO – Research Use Only