tert-Butyl hydroperoxide, 70% aq. soln.


Overview
Brand: Alfa Aesar

Manufacturer Part Number: A13926-AP

TERT-BUTYL HYDROPEROXIDE, 70% AQ, SOLN,500ML

UNSPSC: 12352103

Code: NEW

Additional Details:
Additional Details: CAS Number: 75-91-2 Weight: 0.01000kg


Quantity 500mL

Product Code. 11461648

Quantity Price
1 £ 28.3 / 500mL
Estimated Shipment date
from Supplier 14-12-2016
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Description and Specification

Chemical Identifiers

Chemical Name or Material tert-Butyl Hydroperoxide
CAS 75-91-2
Molecular Formula (CH3)3C-OOH
Linear Formula (CH3)3COOH
Formula Weight 90.12g/mol
MDL Number MFCD00002130
UN Number UN3109
Beilstein 1098280
Merck Index 14,1570

Specification

Density 0.937
Quantity 500mL
Chemical Name or Material tert-Butyl Hydroperoxide
CAS 75-91-2
Assay Percent Range 70% Aqueous Solution
Molecular Formula (CH3)3C-OOH
Linear Formula (CH3)3COOH
Formula Weight 90.12g/mol
MDL Number MFCD00002130
UN Number UN3109
Beilstein 1098280
Merck Index 14,1570
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H300-H310-H330-H314-H226-H242
Fatal if swallowed.
Fatal in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
Flammable liquid and vapour.
Heating may cause a fire.
Health Hazard 3 GHS P Statement
P210-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P361-P405-P410-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
Recommended Storage 2° to 8°C
DOT Information Transport Hazard Class: 5.2; Packing Group: II; Proper Shipping Name: ORGANIC PEROXIDE TYPE F, LIQUID
RTECS Number EQ4900000
TSCA TSCA

Applications
tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.

Solubility
Miscible with water and diethyl ether.

Notes
Light sensitive. Store in cool place. Incompatible with powdered metals, strong oxidizing agents, reducing agents, acids, alkalis and heavy metals.

Safety and Handling

Danger

GHS H Statement
H300-H310-H330-H314-H226-H242
Fatal if swallowed.
Fatal in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
Flammable liquid and vapour.
Heating may cause a fire.

GHS P Statement
P210-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P361-P405-P410-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

2° to 8°C