(S)-(-)-2-Methyl-CBS-oxazaborolidine, 1M solution in toluene, AcroSeal™

Description

CAS: 112022-81-8 | C18H20BNO | 277.17 g/mol

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Reduction reagent

Specifications

• CAS: 112022-81-8, 108-88-3
• CAS Min %: 26.85, 67.18
• CAS Max %: 32.82, 73.15
• Color: Amber to Colorless
• Density: 0.9290g/mL
• Boiling Point: 111.0°C
• Flash Point: 4°C
• Packaging: AcroSeal™ Glass Bottle
• Molecular Formula: C18H20BNO
• MDL Number: MFCD00078439
• Quantity: 50 mL
• Specific Gravity: 0.929
• Synonym: s-2-methyl-cbs-oxazaborolidine, s-methyl oxazaborolidine, s---2-methyl-cbs-oxazaborolidine, s-5,5-diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine, corey catalyst, s-methyl-cbs-oxazaborolidine, s-3,3-diphenyl-1-methylpyrrolidino 1,2-c-1,3,2-oxazaborole, s-me-cbs catalyst, s-methyl-cbs, s-me-cbs
• Solubility Information: Solubility in water: reacts
• InChI Key: VMKAFJQFKBASMU-KRWDZBQOSA-N
• SMILES: [H][C@@]12CCCN1B(C)OC2(C1=CC=CC=C1)C1=CC=CC=C1
• IUPAC Name: (3aS)-1-methyl-3,3-diphenyl-3a,4,5,6-tetrahydropyrrolo[1,2-c][1,3,2]oxazaborole
• Molecular Weight (g/mol): 277.17
• PubChem CID: 2734713
• Formula Weight: 277.17
• Physical Form: Liquid
• Chemical Name or Material: (S)-(-)-2-Methyl-CBS-oxazaborolidine

Safety and Handling

Product Identifier

• (S)-2-Methyl-CBS-oxazaborolidine, 1M solution in toluene

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Aspiration toxicity Category 1
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Reproductive toxicity Category 2
• Skin corrosion/irritation Category 2
• Specific target organ toxicity after repeated exposure Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H304-May be fatal if swallowed and enters airways.
• H318-Causes serious eye damage.
• H315-Causes skin irritation.
• H361d-Suspected of damaging the unborn child.
• H373-May cause damage to organs.
• H336-May cause drowsiness or dizziness.
• H302-Harmful if swallowed.
• H225-Highly flammable liquid and vapour.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

SDS

RUO – Research Use Only