Potassium tri-sec-butylborohydride, 1M solution in tetrahydrofuran, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10082690	Thermo Scientific Acros 205471000	100 mL	AcroSeal glass bottle
10381384	Thermo Scientific Acros 205478000	800 mL	AcroSeal™ Glass bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Reduction reagent

Specifications

• Chemical Name or Material: Potassium tri-sec-butylborohydride
• CAS: 54575-49-4, 109-99-9
• Density: 0.9100g/mL
• Linear Formula: KB[CH(CH₃)C₂H₅]₃H
• Fieser: 06,490; 07,307
• Synonym: k-selectride, potassium tri-sec-butylborohydride solution, k-selectride™ solution, k-selectride r solution 1.0 m potassium tri-sec-butylborohydride in thf, k-selectride r solution, 1.0 m potassium tri-sec-butylborohydride in thf, potassium tri-sec-butylborohydride, 1.0m in thf, in sure/seal tm bottle
• SMILES: [H-].[B+3].[K+].CC[CH-]C.CC[CH-]C.CC[CH-]C
• Molecular Weight (g/mol): 222.26
• Physical Form: Solution

• Name Note: 1M Solution in tetrahydrofuran
• Color: Yellow
• Molecular Formula: C12H28BK
• MDL Number: MFCD00009324
• Merck Index: 15, 8564
• InChI Key: UHNDOQOAVCJJPO-UHFFFAOYSA-N
• IUPAC Name: boron(3+) potassium tris(butan-2-ide) hydride
• Formula Weight: 222.26

Safety and Handling

GHS P Statement Highly flammable liquid and vapour. In contact with water releases flammable gases which may ignite spontaneously. Causes severe skin burns and eye damage. May cause respiratory irritation. Reacts viol

GHS P Statement Keep away from any possible contact with water, because of violent reaction and possible flash fire. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiou

Danger

Recommended Storage : Product may darken on storage

Product Identifier

• Potassium tri-sec-butylborohydride, 1 M solution in tetrahydrofuran

Signal Word

• Danger

Hazard Category

• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H351-Suspected of causing cancer.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P231+P232-Handle under inert gas. Protect from moisture.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only