Alfa Aesar™ Phenyl phosphorodichloridate, 97%


Overview
Brand: Alfa Aesar™

Manufacturer Part Number: A10479.14

UNSPSC: 12352128

Code: NEW

Additional Details:
Additional Details: CAS Number: 770-12-7 Weight: 0.01000kg


Quantity 25g

Product Code. 11408723

Quantity Price
1 £ 19.5 / 25g
Estimated Shipment date
from Supplier 06-04-2017
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Description and Specification

Chemical Identifiers

Chemical Name or Material Phenyl phosphorodichloridate
CAS 770-12-7
Molecular Formula C6H5Cl2O2P
Formula Weight 210.98
MDL Number MFCD00002067
UN Number UN3265
Beilstein 511863
Synonym Phenyl dichlorophosphate

Specification

Formula Weight 210.98
Health Hazard 3 GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF SWALLOWED: Rinse mouth.
Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
UN Number UN3265
Quantity 25g
MDL Number MFCD00002067
Boiling Point 241° to 243°C
RTECS Number TD4393000
TSCA TSCA
Assay 97%
Molecular Formula C6H5Cl2O2P
Flash Point 112°C (233°F)
Synonym Phenyl dichlorophosphate
Beilstein 511863
Chemical Name or Material Phenyl phosphorodichloridate
CAS 770-12-7
Melting Point −1°C
Health Hazard 1 Danger
DOT Information Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Health Hazard 2 GHS H Statement
H314-H318-H302
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.

Applications
Reagent for preparation of phosphate diesters.Phenyl phosphorodichloridate is used in the preparation of symmetrical phosphate diesters. It is used as a phosphorylating agent for alcohols and amines. It is also involved in the preparation of phenylphosphoro di-(1-imidazolidate) and 2-phenyl-bis-triazoloylphosphate, which is used in peptide synthesis. It plays a vital role in the Pfitzner-Moffatt oxidation which involves oxidation of alcohols to the corresponding aldehydes and ketones. Furthermore, it is utilized in Beckmann rearrangement for the preparation of N-phenylacetamide from acetophenone oxime.

Solubility
Immiscible with water.

Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases, alcohols and strong oxidizing agents.

Documentation

Technical documents

Safety and Handling

Danger

GHS H Statement
H314-H318-H302
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.

GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF SWALLOWED: Rinse mouth.
Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.