Phenyl phosphorodichloridate, 97%

Artikelnummer. 11428723

Marke: Thermo Scientific Alfa Aesar A10479.36

Beschreibung

CAS: 770-12-7 | C6H5Cl2O2P | 210.978 g/mol

Reagent for preparation of phosphate diesters.Phenyl phosphorodichloridate is used in the preparation of symmetrical phosphate diesters. It is used as a phosphorylating agent for alcohols and amines. It is also involved in the preparation of phenylphosphoro di-(1-imidazolidate) and 2-phenyl-bis-triazoloylphosphate, which is used in peptide synthesis. It plays a vital role in the Pfitzner-Moffatt oxidation which involves oxidation of alcohols to the corresponding aldehydes and ketones. Furthermore, it is utilized in Beckmann rearrangement for the preparation of N-phenylacetamide from acetophenone oxime.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Reagent for preparation of phosphate diesters.Phenyl phosphorodichloridate is used in the preparation of symmetrical phosphate diesters. It is used as a phosphorylating agent for alcohols and amines. It is also involved in the preparation of phenylphosphoro di-(1-imidazolidate) and 2-phenyl-bis-triazoloylphosphate, which is used in peptide synthesis. It plays a vital role in the Pfitzner-Moffatt oxidation which involves oxidation of alcohols to the corresponding aldehydes and ketones. Furthermore, it is utilized in Beckmann rearrangement for the preparation of N-phenylacetamide from acetophenone oxime.

Solubility
Immiscible with water.

Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases, alcohols and strong oxidizing agents.

Spezifikation

Chemische Identifikatoren

• CAS: 770-12-7
• Molecular Formula: C6H5Cl2O2P
• Molecular Weight (g/mol): 210.978
• MDL Number: MFCD00002067
• InChI Key: TXFOLHZMICYNRM-UHFFFAOYSA-N
• Synonym: phenyl dichlorophosphate, phenyl phosphorodichloridate, dichlorophenoxyphosphine oxide, phosphorodichloridic acid, phenyl ester, phenylphosphoric dichloride, phenyl phosphorodichlorodate, phenoxydichlorophosphine oxide, phenyldichlorophosphate, phenoxyphosphoryl dichloride, phosphoroyl dichloride phenyl ester
• PubChem CID: 13038
• IUPAC Name: dichlorophosphoryloxybenzene
• SMILES: C1=CC=C(C=C1)OP(=O)(Cl)Cl

• Melting Point: -1°C
• Density: 1.415
• Boiling Point: 241°C to 243°C
• Flash Point: 112°C (233°F)
• Refractive Index: 1.523
• Quantity: 500 g
• UN Number: UN3265
• Beilstein: 511863
• Sensitivity: Moisture sensitive
• Solubility Information: Immiscible with water.
• Formula Weight: 210.98
• Percent Purity: 97%
• Chemical Name or Material: Phenyl phosphorodichloridate

Sicherheit und Handhabung

Sicherheitsdatenblatt (SDS)

RUO – Research Use Only