Alfa Aesar™ Phenyl phosphorodichloridate, 97%


Overview
Brand: Alfa Aesar™

Manufacturer Part Number: A10479.22

UNSPSC: 12352128

Code: NEW

Additional Details:
Additional Details: CAS Number: 770-12-7 Weight: 0.01000kg


Quantity 100g

Product Code. 11418723

Quantity Price
1 £ 48.97 / 100g
Estimated Shipment date
from Supplier 16-05-2017
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Description and Specification

Chemical Identifiers

Chemical Name or Material Phenyl phosphorodichloridate
CAS 770-12-7
Molecular Formula C6H5Cl2O2P
Formula Weight 210.98
MDL Number MFCD00002067
UN Number UN3265
Beilstein 511863
Synonym Phenyl dichlorophosphate

Specification

Chemical Name or Material Phenyl phosphorodichloridate
Quantity 100g
CAS 770-12-7
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H314-H318-H302
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.
Health Hazard 3 GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF SWALLOWED: Rinse mouth.
Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
DOT Information Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
RTECS Number TD4393000
TSCA TSCA
Assay 97%
Molecular Formula C6H5Cl2O2P
Formula Weight 210.98
MDL Number MFCD00002067
UN Number UN3265
Beilstein 511863
Synonym Phenyl dichlorophosphate
Boiling Point 241° to 243°C
Melting Point −1°C
Flash Point 112°C (233°F)

Applications
Reagent for preparation of phosphate diesters.Phenyl phosphorodichloridate is used in the preparation of symmetrical phosphate diesters. It is used as a phosphorylating agent for alcohols and amines. It is also involved in the preparation of phenylphosphoro di-(1-imidazolidate) and 2-phenyl-bis-triazoloylphosphate, which is used in peptide synthesis. It plays a vital role in the Pfitzner-Moffatt oxidation which involves oxidation of alcohols to the corresponding aldehydes and ketones. Furthermore, it is utilized in Beckmann rearrangement for the preparation of N-phenylacetamide from acetophenone oxime.

Solubility
Immiscible with water.

Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases, alcohols and strong oxidizing agents.

Documentation

Technical documents

Safety and Handling

Danger

GHS H Statement
H314-H318-H302
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.

GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF SWALLOWED: Rinse mouth.
Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.