n-Butyllithium, 2.5M solution in hexanes, AcroSeal™, ACROS Organics™

Brand:  Acros Organics 213351000

Product Code. 10030462

Chemical Identifiers

• CAS: 109-72-8
• Molecular Weight (g/mol): 64.056
• InChI Key: DLEDOFVPSDKWEF-UHFFFAOYSA-N
• PubChem CID: 61028
• SMILES: [Li+].CCC[CH2-]

• Molecular Formula: C4H9Li
• MDL Number: MFCD00009414
• Synonym: n-butyllithium, lithium, butyl, butyllithium, butyl lithium, n-butyl lithium, lithium butane, n-buli, buli, libu, unii-09w9a6b8zc
• IUPAC Name: lithium;butane

Specifications

• Chemical Name or Material: n-Butyllithium
• Flash Point: −21°C
• Specific Gravity: 0.69
• Melting Point: -95.0°C
• Name Note: 2.5M Solution in Hexanes
• Molecular Formula: C4H9Li
• MDL Number: MFCD00009414
• Synonym: n-butyllithium, lithium, butyl, butyllithium, butyl lithium, n-butyl lithium, lithium butane, n-buli, buli, libu, unii-09w9a6b8zc
• SMILES: [Li+].CCC[CH2-]
• Molecular Weight (g/mol): 64.056
• Formula Weight: 64.06

• Density: 0.6900g/mL
• Packaging: AcroSeal™ Glass bottle
• Boiling Point: 60.0°C to 80.0°C
• Quantity: 100mL
• CAS: 110-54-3
• Linear Formula: CH₃(CH₂)₃Li
• Fieser: 01,95; 02,51; 04,60; 05,78; 06,85; 07,45; 08,65; 09,83; 10,68; 11,101; 12,96; 13,56; 14,63; 15,59; 16,55; 17,59
• InChI Key: DLEDOFVPSDKWEF-UHFFFAOYSA-N
• IUPAC Name: lithium;butane
• PubChem CID: 61028

Safety and Handling

Product Identifier

• n-Butyllithium, 2.5M solution in hexanes

Signal Word

• Danger

Hazard Category

• LONG-TERM AQUATIC HAZARD Chronic 2
• Aspiration toxicity Category 1
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Pyrophoric liquid Category 1
• Reproductive toxicity Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity after repeated exposure Category 2
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H304-May be fatal if swallowed and enters airways.
• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H361f-Suspected of damaging fertility.
• H373-May cause damage to organs.
• H411-Toxic to aquatic life with long lasting effects.
• H336-May cause drowsiness or dizziness.
• H250-Catches fire spontaneously if exposed to air.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P222-Do not allow contact with air.
• P240-Ground/bond container and receiving equipment.
• P243-Take precautionary measures against static discharge.
• P260-Do not breathe dust/fume/gas/mist/vapours/spray.
• P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
• P273-Avoid release to the environment.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.
• P331-Do NOT induce vomiting.
• P402+P404-Store in a dry place. Store in a closed container.
• P403+P235-Store in a well-ventilated place. Keep cool.