Methyllithium, 2.2M (6wt%) in diethyl ether with LiBr, AcroSeal™, Thermo Scientific Chemicals

Product Code. 10547383

Brand: Thermo Scientific Acros 181291000

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 917-54-4, 60-29-7
• Molecular Formula: CH3Li
• Molecular Weight (g/mol): 21.98
• MDL Number: MFCD00008253
• InChI Key: DVSDBMFJEQPWNO-UHFFFAOYSA-N
• Synonym: methyllithium, lithium, methyl, methyl lithium, lithium methanide, meli, lithium methyl, lithium carbanide, lithium methide, methllithium, methyllithum
• PubChem CID: 2724049
• IUPAC Name: lithium;carbanide
• SMILES: [Li]C

• Color: Colorless through Yellow
• Physical Form: Solution
• Quantity: 100 mL
• Linear Formula: CH₃Li
• Flash Point: −28°C
• Solubility Information: Solubility in water: vigorous reaction
• Formula Weight: 21.98
• Percent Purity: 9.0 to 11.0% (LiBr), 6.0 to 7.0% (LiCH3)
• Packaging: AcroSeal™ Glass bottle
• Specific Gravity: 0.81
• Density: 0.8100g/mL
• Chemical Name or Material: Methyllithium

Safety and Handling

Product Identifier

• Methyllithium, 2.2M (6wt%) in diethyl ether with lithiumbromide

Signal Word

• Danger

Hazard Category

• Flammable liquid Category 1
• Pyrophoric solid Category 1
• Substance which\, in contact with water\, emits flammable gases Category 1
• Acute toxicity Category 4
• Skin corrosion/irritation Category 1 B
• Serious eye damage/eye irritation Category 1
• Specific target organ toxicity Category 3
• Skin sensitiser Category 1

Hazard Statement

• H224-Extremely flammable liquid and vapour.
• H250-Catches fire spontaneously if exposed to air.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H302-Harmful if swallowed.
• H314-Causes severe skin burns and eye damage.
• H317-May cause an allergic skin reaction.
• H336-May cause drowsiness or dizziness.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.
• EUH066-Repeated exposure may cause skin dryness or cracking.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P231+P232-Handle under inert gas. Protect from moisture.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P310-Immediately call a POISON CENTER/doctor/.

Supplemental information

• MIXTURE LIST-Contains : Lithium bromide (LiBr), Lithium, methyl-, Ethyl ether

SDS

RUO – Research Use Only