Methyl phenylsulfonylacetate, 98%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11306646	Thermo Scientific Alfa Aesar L03748.06	5 g
11316646	Thermo Scientific Alfa Aesar L03748.14	25 g

Description

Methyl phenylsulfonylacetate has been used in a key step during the synthesis of (-)-hybridalactone, marine eicosanoid isolated from the red alga Laurencia hybrida, in dehydrative alkylation of alcohols under modified Mitsunobu conditions followed by desulfonylation using magnesium, in three step synthesis of 2-(hydroxymethyl)indene.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Methyl phenylsulfonylacetate has been used in a key step during the synthesis of (-)-hybridalactone, marine eicosanoid isolated from the red alga Laurencia hybrida, in dehydrative alkylation of alcohols under modified Mitsunobu conditions followed by desulfonylation using magnesium, in three step synthesis of 2-(hydroxymethyl)indene.

Solubility
Insoluble in water.

Notes
Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Chemical Identifiers

• CAS: 34097-60-4
• Molecular Weight (g/mol): 214.235
• InChI Key: NLEAIFBNKPYTGN-UHFFFAOYSA-N
• IUPAC Name: methyl 2-(benzenesulfonyl)acetate

• Molecular Formula: C9H10O4S
• MDL Number: MFCD00007555
• PubChem CID: 555619
• SMILES: COC(=O)CS(=O)(=O)C1=CC=CC=C1

Specifications

• CAS: 34097-60-4
• Density: 1.24
• Flash Point: >110°C (230°F)
• Refractive Index: 1.535
• Beilstein: 2051463
• Solubility Information: Insoluble in water.
• SMILES: COC(=O)CS(=O)(=O)C1=CC=CC=C1
• Molecular Weight (g/mol): 214.235
• Formula Weight: 214.24
• Chemical Name or Material: Methyl phenylsulfonylacetate

• Melting Point: ∼30°C
• Boiling Point: 165°C (0.05 mmHg)
• Molecular Formula: C9H10O4S
• MDL Number: MFCD00007555
• Synonym: methyl phenylsulfonylacetate, methyl 2-phenylsulfonyl acetate, methyl phenylsulfonyl acetate, methylphenylsulfonylacetate, benzenesulfonyl-acetic acid methyl ester, acmc-1ad0h, methyl benzenesulfonylacetate, methyl2-phenylsulfonyl acetate, methyl-phenylsulfonyl acetate
• InChI Key: NLEAIFBNKPYTGN-UHFFFAOYSA-N
• IUPAC Name: methyl 2-(benzenesulfonyl)acetate
• PubChem CID: 555619
• Percent Purity: 98%

Safety and Handling

missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures

RUO – Research Use Only