Alfa Aesar™ m-Anisidine, 98%


Overview
Brand: Alfa Aesar™

Manufacturer Part Number: A10815.0B

UNSPSC: 12352116

Code: NEW

Additional Details:
Additional Details: CAS Number: 536-90-3 Weight: 0.01000kg


Quantity 1000g

Product Code. 11449752

Quantity Price
1 £ 164.82999999999998 / 1000g
Estimated Shipment date
from Supplier 10-04-2017
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Description and Specification

Chemical Identifiers

Chemical Name or Material m-Anisidine
CAS 536-90-3
Molecular Formula C7H9NO
Formula Weight 123.16
MDL Number MFCD00007783
UN Number UN2431
Beilstein 386119
Merck Index 14,667
Synonym 3-Aminoanisole; 3-Methoxyaniline

Specification

Formula Weight 123.16
Health Hazard 3 GHS P Statement
P280h-P273-P309-P310-P302+P352-P501a
Wear protective gloves/clothing.
Avoid release to the environment.
IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
IF ON SKIN: Wash with plenty of soap and water.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical Name or Material m-Anisidine
DOT Information Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: ANISIDINES
Melting Point −1°C
UN Number UN2431
Assay 98%
Quantity 1000g
Health Hazard 1 Danger
Merck Index 14,667
TSCA TSCA
CAS 536-90-3
Synonym 3-Aminoanisole; 3-Methoxyaniline
Molecular Formula C7H9NO
Boiling Point 250° to 251°C
MDL Number MFCD00007783
Beilstein 386119
Flash Point 126°C (258°F)
RTECS Number BZ5408000
Odor Characteristic
Health Hazard 2 GHS H Statement
H311-H373-H302-H332
Toxic in contact with skin.
May cause damage to organs through prolonged or repeated exposure.
Harmful if swallowed.
Harmful if inhaled.

Applications
The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

Solubility
Soluble in water(18g/L).

Notes
Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Documentation

Technical documents

Safety and Handling

Danger

GHS H Statement
H311-H373-H302-H332
Toxic in contact with skin.
May cause damage to organs through prolonged or repeated exposure.
Harmful if swallowed.
Harmful if inhaled.

GHS P Statement
P280h-P273-P309-P310-P302+P352-P501a
Wear protective gloves/clothing.
Avoid release to the environment.
IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
IF ON SKIN: Wash with plenty of soap and water.
Dispose of contents/container in accordance with local/regional/national/international regulations.