m-Anisidine, 98%, Thermo Scientific Chemicals

Description

The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

Solubility
Soluble in water(18g/L).

Notes
Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 536-90-3
• Molecular Formula: C7H9NO
• Molecular Weight (g/mol): 123.155
• MDL Number: MFCD00007783
• InChI Key: NCBZRJODKRCREW-UHFFFAOYSA-N
• Synonym: m-anisidine, 3-aminoanisole, m-methoxyaniline, 3-methoxybenzenamine, 3-anisidine, m-aminoanisole, benzenamine, 3-methoxy, m-anisylamine, 1-amino-3-methoxybenzene, unii-jxa144kx2i
• PubChem CID: 10824
• IUPAC Name: 3-methoxyaniline
• SMILES: COC1=CC=CC(=C1)N

• Melting Point: -1°C
• Density: 1.101
• Boiling Point: 250°C to 251°C
• Flash Point: 126°C (258°F)
• Odor: Characteristic
• Refractive Index: 1.581
• Quantity: 1000 g
• UN Number: UN2431
• Beilstein: 386119
• Sensitivity: Light sensitive
• Merck Index: 14,667
• Solubility Information: Soluble in water(18g/L).
• Formula Weight: 123.16
• Percent Purity: 98%
• Chemical Name or Material: m-Anisidine

RUO – Research Use Only