Lithium tert-butoxide, 99%

Product Code.	Quantity	Unit Size
15412677	250 g	250g
15422677	1 kg	1kg

Product Code. 15412677 Supplier Thermo Scientific Alfa Aesar Supplier No. 046366.30

Description

CAS: 1907-33-1 | C4H9LiO | 80.055 g/mol

Lithium tert-butoxide is a mild base used in organic synthesis. It is involved in the alfa-alkylation reaction of ketones with primary alcohols. It is utilized as a catalyst in the reduction of ketones to the corresponding secondary alcohols. It acts as lithium source utilized in the preparation of Li_xTi_yO_z thin films. Further, it is used in conjunction with organometallic reagents/catalysts to modify their reactivity and selectivity.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Spécification

Identifiants chimiques

• CAS: 1907-33-1
• Molecular Formula: C4H9LiO
• Molecular Weight (g/mol): 80.055
• MDL Number: MFCD00050479
• InChI Key: LZWQNOHZMQIFBX-UHFFFAOYSA-N
• Synonym: lithium tert-butoxide, lithium 2-methylpropan-2-olate, tert-butoxylithium, lithium tert-butylate, lithium tert-butanolate, tert-butyl alcohol, lithium salt, lithium t-butoxide, 2-methyl-2-propanol lithium salt, 2-propanol, 2-methyl-, lithium salt, lithium 1+ ion 2-methylpropan-2-olate
• PubChem CID: 23664764
• IUPAC Name: lithium;2-methylpropan-2-olate
• SMILES: [Li+].CC(C)(C)[O-]

• Melting Point: ∼150°C (decomposition)
• Color: White to Cream
• Odor: Odorless
• Linear Formula: (CH₃)₃COLi
• Quantity: 250 g
• UN Number: UN3206
• Beilstein: 3620018
• Sensitivity: Air and moisture sensitive
• Solubility Information: Soluble in toluene,hexane,tetrahydrofuran and methyl tert-butyl ether.
• Formula Weight: 80.06
• Percent Purity: 99%
• Physical Form: Powder
• Chemical Name or Material: Lithium tert-butoxide

Sécurité et traitement

Identifiant produit

• Lithium tert-butoxide

Mention d'avertissement

• Danger

Catégorie de danger

• Acute toxicity Category 4
• Serious eye damage/eye irritation Category 1
• Flammable solid Category 2
• Skin corrosion/irritation Category 1 B

Mention de danger

• H228-Flammable solid.
• H302-Harmful if swallowed.
• H314-Causes severe skin burns and eye damage.
• H318-Causes serious eye damage.
• EUH014-Reacts violently with water.

Conseils de prudence

• P235+P410-Keep cool. Protect from sunlight.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

Informations supplémentaires

• MIXTURE LIST-Contain: Lithium tert-butoxide

FDS

RUO – Research Use Only