Hexamethylphosphorous triamide, 97%

Product Code. 11451900

Brand: Thermo Scientific Alfa Aesar A12571.06

Description

CAS: 1608-26-0 | C6H18N3P | 163.21 g/mol

Hexamethylphosphorous triamide is used as a reagent in organic synthesis as a phosphorylating agent. It is associated with carbon tetrachloride for the substitution of hydroxy groups with chlorides. It is involved in the preparation of epoxides and arene oxides from aldehydes and aryldialdehdyes respectively. It is used in the preparation of carbonates as well as reduction of ozonides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Hexamethylphosphorous triamide is used as a reagent in organic synthesis as a phosphorylating agent. It is associated with carbon tetrachloride for the substitution of hydroxy groups with chlorides. It is involved in the preparation of epoxides and arene oxides from aldehydes and aryldialdehdyes respectively. It is used in the preparation of carbonates as well as reduction of ozonides.

Solubility
Miscible with water.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 1608-26-0
• Molecular Formula: C6H18N3P
• Molecular Weight (g/mol): 163.21
• MDL Number: MFCD00008301
• InChI Key: XVDBWWRIXBMVJV-UHFFFAOYSA-N
• Synonym: hexamethylphosphorous triamide, tris dimethylamino phosphine, hexametapil, phosphorous triamide, hexamethyl, hexamethyltriamidophosphite, hexamethyltriaminophosphine, phosphine, tris dimethylamino, bis dimethylamino phosphanyl dimethylamine, hmpt van, hexamethyl phosphorus triamide
• PubChem CID: 15355
• IUPAC Name: N-[bis(dimethylamino)phosphanyl]-N-methylmethanamine
• SMILES: CN(C)P(N(C)C)N(C)C

• Melting Point: -44°C
• Density: 0.898
• Boiling Point: 162°C to 164°C
• Flash Point: 37°C (98°F)
• Refractive Index: 1.465
• Quantity: 5 g
• UN Number: UN1993
• Beilstein: 906778
• Sensitivity: Air sensitive; May form a precipitate
• Solubility Information: Miscible with water.
• Formula Weight: 163.21
• Percent Purity: 97%
• Chemical Name or Material: Hexamethylphosphorous triamide

Safety and Handling

SDS

RUO – Research Use Only