Ethyl (ethoxymethylene)cyanoacetate, 98%, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10626882	Thermo Scientific Acros 118481000	100 g	Glass bottle
10636882	Thermo Scientific Acros 118485000	500 g	Glass bottle
10667963	Thermo Scientific Acros 118480010	1 kg	Glass bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 94-05-3
• Molecular Weight (g/mol): 169.18
• InChI Key: KTMGNAIGXYODKQ-SREVYHEPSA-N
• PubChem CID: 1715183

• Molecular Formula: C8H11NO3
• MDL Number: MFCD00009136
• Synonym: ethyl ethoxymethylene cyanoacetate, e-ethyl 2-cyano-3-ethoxyacrylate, ethyl 2-cyano-3-ethoxyacrylate, ethyl 3-ethoxy-2-cyanoacrylate, ethyl 2e-2-cyano-3-ethoxyprop-2-enoate, ethyl cyano ethoxymethylene acetate, 2-propenoic acid, 2-cyano-3-ethoxy-, ethyl ester, 2-cyano-3-ethoxy-2-propenoic acid ethyl ester, 2-cyano-3-ethoxyacrylic acid ethyl ester, ethyl 2e-2-cyano-3-ethoxy-2-propenoate
• SMILES: CCO\C=C(\C#N)C(=O)OCC

Specifications

• CAS: 94-05-3
• Color: White to Yellow
• Flash Point: 130°C
• Assay Percent Range: 97.5% min. (GC)
• Linear Formula: C₂H₅OCH=C(CN)CO₂C₂H₅
• Beilstein: 03,47
• Synonym: ethyl ethoxymethylene cyanoacetate, e-ethyl 2-cyano-3-ethoxyacrylate, ethyl 2-cyano-3-ethoxyacrylate, ethyl 3-ethoxy-2-cyanoacrylate, ethyl 2e-2-cyano-3-ethoxyprop-2-enoate, ethyl cyano ethoxymethylene acetate, 2-propenoic acid, 2-cyano-3-ethoxy-, ethyl ester, 2-cyano-3-ethoxy-2-propenoic acid ethyl ester, 2-cyano-3-ethoxyacrylic acid ethyl ester, ethyl 2e-2-cyano-3-ethoxy-2-propenoate
• InChI Key: KTMGNAIGXYODKQ-SREVYHEPSA-N
• IUPAC Name: ethyl (2Z)-2-cyano-3-ethoxyprop-2-enoate
• PubChem CID: 1715183
• Percent Purity: 98%
• Chemical Name or Material: Ethyl (ethoxymethylene)cyanoacetate, 98%

• Melting Point: 48°C to 52°C
• Boiling Point: 190°C to 191°C (30.0 mmHg)
• Infrared Spectrum: Authentic
• Molecular Formula: C8H11NO3
• MDL Number: MFCD00009136
• Fieser: 01,38
• Solubility Information: Solubility in water: <0.01g/L (20°C)
• SMILES: CCO\C=C(\C#N)C(=O)OCC
• Molecular Weight (g/mol): 169.18
• Formula Weight: 169.18
• Physical Form: Crystalline Mass or Crystals

Safety and Handling

GHS H Statement
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Causes serious eye damage.
May cause an allergic skin reaction.
May cause respiratory irritation.
Harmful if swallowed.
Causes

GHS P Statement
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses,if present and easy to do.
Continue rinsing.
Immediately call a POISON CENTER or doctor/physician.
Avoid breathing dust/fume/gas/mis

GHS Signal Word: Danger

missing translation for 'einecsNumber' : 202-299-5

missing translation for 'tsca' : TSCA

Product Identifier

• Ethyl (ethoxymethylene)cyanoacetate

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Serious eye damage/eye irritation Category 1
• Respiratory sensitiser Category 1
• Skin corrosion/irritation Category 2
• Skin sensitiser Category 1
• Specific target organ toxicity Category 3

Hazard Statement

• H317-May cause an allergic skin reaction.
• H318-Causes serious eye damage.
• H334-May cause allergy or asthma symptoms or breathing difficulties if inhaled.
• H315-Causes skin irritation.
• H335-May cause respiratory irritation.
• H302-Harmful if swallowed.

Precautionary Statement

• P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P312-IF SWALLOWED: Call a POISON CENTER or doctor/physician/ if you feel unwell.
• P302+P352-IF ON SKIN: Wash with plenty of water/.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.
• P342+P311-If experiencing respiratory symptoms: Call a POISON CENTER/doctor/ .

RUO – Research Use Only