Ethyl 4-chloroacetoacetate, 98%, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10022380	Thermo Scientific Acros 177640500	50 g	Glass bottle
10183760	Thermo Scientific Acros 177642500	250 g	Glass bottle
11995101	Thermo Scientific Acros 177640010	1 kg	Glass bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 638-07-3
• Molecular Weight (g/mol): 164.59
• InChI Key: OHLRLMWUFVDREV-UHFFFAOYSA-N
• PubChem CID: 69484
• SMILES: CCOC(=O)CC(=O)CCl

• Molecular Formula: C₆H₉ClO₃
• MDL Number: MFCD00000939
• Synonym: ethyl 4-chloroacetoacetate, 4-chloroacetoacetic acid ethyl ester, butanoic acid, 4-chloro-3-oxo-, ethyl ester, ethyl gamma-chloroacetoacetate, unii-5ae82250cm, ccris 6791, ethyl chloroacetyl acetate, butanoic acid, 4-chloro-3-oxo-ethylester, ethyl 4-chloro-3-oxobutyrate, ethyl 4-chloro-3-oxo-butanoate
• IUPAC Name: ethyl 4-chloro-3-oxobutanoate

Specifications

• CAS: 638-07-3
• Color: Colorless to Red-Yellow
• Boiling Point: 103.0°C (16.0 mmHg)
• Infrared Spectrum: Authentic
• Molecular Formula: C₆H₉ClO₃
• Refractive Index: 1.4510 to 1.4530
• Beilstein: 03,663
• Synonym: ethyl 4-chloroacetoacetate, 4-chloroacetoacetic acid ethyl ester, butanoic acid, 4-chloro-3-oxo-, ethyl ester, ethyl gamma-chloroacetoacetate, unii-5ae82250cm, ccris 6791, ethyl chloroacetyl acetate, butanoic acid, 4-chloro-3-oxo-ethylester, ethyl 4-chloro-3-oxobutyrate, ethyl 4-chloro-3-oxo-butanoate
• InChI Key: OHLRLMWUFVDREV-UHFFFAOYSA-N
• IUPAC Name: ethyl 4-chloro-3-oxobutanoate
• PubChem CID: 69484
• Percent Purity: 98%
• Chemical Name or Material: Ethyl 4-chloroacetoacetate, 98%

• Melting Point: -8.0°C
• Density: 1.2100g/mL
• Flash Point: 96°C
• Assay Percent Range: 97.5% min. (GC)
• Linear Formula: ClCH₂COCH₂CO₂C₂H₅
• MDL Number: MFCD00000939
• Specific Gravity: 1.21
• Solubility Information: Solubility in water: 47.5g/L water (20°C). Other solubilities: soluble in ether,benzene,chloroform,,methylenechloride and carbontetrachloride
• SMILES: CCOC(=O)CC(=O)CCl
• Molecular Weight (g/mol): 164.59
• Formula Weight: 164.59
• Physical Form: Liquid

Safety and Handling

GHS H Statement:
Causes severe skin burns and eye damage.
Causes serious eye damage.
Toxic if swallowed.
Toxic in contact with skin.
Toxic to aquatic life with long lasting effects.

GHS P Statement:
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
Wear protective gloves/protective clothing/eye protection/face protection.
Call a POISON CENTER or doctor/physician if you feel unwell.
IF ON SKIN: Gently wash with plenty of soap and water.
IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
Wear eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor/physician.
Avoid release to the environment.

WARNING: The information provided on this web site was developed in compliance with European Union (EU) regulations and is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling and use. It is not to be considered as either a warranty or quality specifi

GHS Signal Word: Danger

missing translation for 'einecsNumber' : 211-317-0

missing translation for 'rtecsNumber' : AK5110000

missing translation for 'tsca' : TSCA

Product Identifier

• Ethyl 4-chloroacetoacetate

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 3
• LONG-TERM AQUATIC HAZARD Chronic 2
• Serious eye damage/eye irritation Category 1
• Skin corrosion/irritation Category 1 B

Hazard Statement

• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H411-Toxic to aquatic life with long lasting effects.
• H311-Toxic in contact with skin.
• H301-Toxic if swallowed.

Precautionary Statement

• P273-Avoid release to the environment.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only