Diiodomethane, 99%, stab.


Overview
Brand: Alfa Aesar

Manufacturer Part Number: A15457-18

METHYLENE IODIDE, STAB. WITH COPPER, 99%,50G

UNSPSC: 12352101

Code: NEW

Additional Details:
Additional Details: CAS Number: 75-11-6 Weight: 0.01000kg


Quantity 50g

Product Code. 11432817

Quantity Price
1 £ 22.37 / 50g
Estimated Shipment date
from Supplier 12-12-2016
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Description and Specification

Chemical Identifiers

Chemical Name or Material Diiodomethane
CAS 75-11-6
Name Note stabilized
Molecular Formula CH2I2
Formula Weight 267.84g/mol
MDL Number MFCD00001079
UN Number UN2810
Beilstein 1696892
Merck Index 14,6066

Specification

Density 3.322
Quantity 50g
Chemical Name or Material Diiodomethane
Name Note stabilized
CAS 75-11-6
Physical Form Liquid
Assay 99%
Assay Percent Range 99%, stab.
Molecular Formula CH2I2
Formula Weight 267.84g/mol
MDL Number MFCD00001079
UN Number UN2810
Beilstein 1696892
Merck Index 14,6066
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H302-H332-H315-H319-H335
Harmful if swallowed.
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for se
DOT Information Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: TOXIC, LIQUIDS, ORGANIC, N.O.S.
RTECS Number PA8575000
TSCA TSCA

Applications
Diiodomethane is used to determine the density of minerals and other solid samples due to its high density. It is used as an optical contact liquid to determine the refractive index of certain gemstones. In simmons-smith reaction, it acts as a reagent to generate methylene (carbine) free radical. It reacts with olefins to prepare cyclopropanes with high stereo specificity.

Solubility
Miscible with alcohol and ether. Slightly miscible with water.

Notes
Light sensitive. Keep container tightly closed in a dry and well-ventilated place. Incompatible with alkali metal salts, strong oxidizing agents, strong bases, metals, lithium, potassium, sodium, sodium oxides and alloys.

Safety and Handling

Warning

GHS H Statement
H302-H332-H315-H319-H335
Harmful if swallowed.
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for se