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(+)-Diethyl L-tartrate, 98%, Thermo Scientific Chemicals

Catalog Number 11474260
61.13 GBP valid until 2024-03-29
Use promo code "21615" to get your promotional price.


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To receive the discount customers must purchase three of the same product at list price in a single order to receive 33.33% discount. There is no limit to the multiples of 3 that customers can buy. Use promo code ”21615” to get your promotional price
87-91-2
C8H14O6
206.19
MFCD00009143
YSAVZVORKRDODB-UHFFFAOYNA-N
diethyl l-+-tartrate, 2r,3r-diethyl 2,3-dihydroxysuccinate, l +-diethyl l-tartrate, +-diethyl l-tartrate, diethyl l-tartrate, diethyl-l-tartrate, unii-oq72cpy58z, l-+-tartaric acid diethyl ester, diethyl l-tartarate, tartaric acid, diethyl ester, r,r
6993580
CCOC(=O)C(O)C(O)C(=O)OCC
This item is not returnable. View return policy
To receive the discount customers must purchase three of the same product at list price in a single order to receive 33.33% discount. There is no limit to the multiples of 3 that customers can buy. Use promo code ”21615” to get your promotional price
87-91-2
C8H14O6
206.19
MFCD00009143
YSAVZVORKRDODB-UHFFFAOYNA-N
diethyl l-+-tartrate, 2r,3r-diethyl 2,3-dihydroxysuccinate, l +-diethyl l-tartrate, +-diethyl l-tartrate, diethyl l-tartrate, diethyl-l-tartrate, unii-oq72cpy58z, l-+-tartaric acid diethyl ester, diethyl l-tartarate, tartaric acid, diethyl ester, r,r
6993580
CCOC(=O)C(O)C(O)C(=O)OCC

(+)-Diethyl L-tartrate is used as a chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols, for Sharpless-type enantioselective oxidation of sulfides to sulfoxides and as a chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols by an asymmetric Simmons-Smith reaction. It is also used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke therapy.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(+)-Diethyl L-tartrate is used as a chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols, for Sharpless-type enantioselective oxidation of sulfides to sulfoxides and as a chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols by an asymmetric Simmons-Smith reaction. It is also used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke therapy.

Solubility
Fully miscible in water.

Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.
TRUSTED_SUSTAINABILITY
Melting Point 17°C
Density 1.205
Boiling Point 280°C
Flash Point 93°C (199°F)
Refractive Index 1.446
Quantity 500 g
Beilstein 1727145
Merck Index 14,3855
Solubility Information Fully miscible in water.
Optical Rotation +27° (c=1 in water)
IUPAC Name diethyl (2R,3R)-2,3-dihydroxybutanedioate
Formula Weight 206.19
Percent Purity 98%
Chemical Name or Material (+)-Diethyl L-tartrate
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