Alfa Aesar™ Diethyl diallylmalonate, 98%


Overview
Brand: Alfa Aesar™

Manufacturer Part Number: A12460-09

DIETHYL DIALLYLMALONATE, 98%,10G

UNSPSC: 12352106

Code: NEW

Additional Details:
Additional Details: CAS Number: 3195-24-2 Weight: 0.01000kg


Quantity 10g

Product Code. 11469693

Quantity Price
1 £ 48.65 / 10g
Estimated Shipment date
from Supplier 07-12-2016
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Description and Specification

Chemical Identifiers

Chemical Name or Material Diethyl diallylmalonate
CAS 3195-24-2
Molecular Formula C13H20O4
Formula Weight 240.30g/mol
MDL Number MFCD00009126
Beilstein 1790529
Synonym Diallylmalonic acid diethyl ester

Specification

Boiling Point 242° to 244°C
Flash Point >110°C (230°F)
Quantity 10g
Chemical Name or Material Diethyl diallylmalonate
CAS 3195-24-2
Assay 98%
Molecular Formula C13H20O4
Formula Weight 240.30g/mol
MDL Number MFCD00009126
Beilstein 1790529
Synonym Diallylmalonic acid diethyl ester
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Applications
Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.

Solubility
Sparingly Soluble in water. (0.72 g/L) (25°C)

Notes
Store under cool dry place. Ensure good ventilation.

Safety and Handling

Warning

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.