Alfa Aesar™ Diethyl diallylmalonate, 98%


Overview
Brand: Alfa Aesar™

Manufacturer Part Number: A12460.30

DIETHYL DIALLYLMALONATE, 98%,250G

UNSPSC: 12352106

Code: NEW

Additional Details:
Additional Details: CAS Number: 3195-24-2 Weight: 0.01000kg


Quantity 250g

Product Code. 11489693

Quantity Price
1 £ 676.81 / 250g
Estimated Shipment date
from Supplier 01-02-2017
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Description and Specification

Chemical Identifiers

Chemical Name or Material Diethyl diallylmalonate
CAS 3195-24-2
Molecular Formula C13H20O4
Formula Weight 240.3
MDL Number MFCD00009126
Beilstein 1790529
Synonym Diallylmalonic acid diethyl ester

Specification

Formula Weight 240.3
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical Name or Material Diethyl diallylmalonate
Assay 98%
Molecular Formula C13H20O4
MDL Number MFCD00009126
CAS 3195-24-2
Boiling Point 242° to 244°C
Beilstein 1790529
Flash Point >110°C (230°F)
Synonym Diallylmalonic acid diethyl ester
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Quantity 250g

Applications
Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.

Solubility
Sparingly Soluble in water. (0.72 g/L) (25°C)

Notes
Store under cool dry place. Ensure good ventilation.

Safety and Handling

Warning

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.