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Alfa Aesar™ Diethyl acetone-1,3-dicarboxylate, 96%

Brand:  Alfa Aesar™ A10933.18

UNSPSC : 12352106

Code : NEW

Additional Details : CAS Number : 105-50-0 Weight : 0.05000kg

Quantity 50g

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Product Code. 11404343

  • £28.83 / 50g


Estimated Shipment date
from Supplier 10-08-2017
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Specifications

Description

Applications
Synthesis of 1-substituted 4-ethoxycarbonyl-5- (ethoxycarbonylmethyl) pyrazoles Diethyl acetone-1, 3-dicarboxylate reacts with N, N-dimethylforma- mide dimethyl acetal (DMFDMA) in ethanol at room temperature. Unexpected product dichotomy is produced in the Biginelli-like condensation of 2-hydroxybenzaldehyde with urea or thiourea and dimethyl or diethyl acetone-1,3-dicarboxylate, respectively, as active methylene components. Ethyl 2-amino-4-(2-ethoxy-2-oxoethyl)thiazole-5-carboxylate (2a), prepared from diethylacetone-1,3-dicarboxylate, sulfuryl chloride and thiourea. Synthesis of diethyl 2,2-diethyl-3,5-dioxopimelate by the reaction of ethyl 3-chloro-3-oxo-2,2-dimethylpropionate with diethyl acetone-1,3-dicarboxylate.

Solubility
Insoluble in water and soluble in alcohol, ester, benzene.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
Description & Specifications

Chemical Identifiers

Diethyl acetone-1,3-dicarboxylate
C9H14O5
MFCD00009200
Acetone-1,3-dicarboxylic acid diethyl ester; Diethyl 3-oxoglutarate
105-50-0
202.21
640146

Specifications

Diethyl acetone-1,3-dicarboxylate
105-50-0
C9H14O5
MFCD00009200
640146
Acetone-1,3-dicarboxylic acid diethyl ester; Diethyl 3-oxoglutarate
50g
96%
202.21
134° to 135°C (10mmHg)
86°C (186°F)
Documentation

Technical Documents