Alfa Aesar™ Diethyl acetone-1,3-dicarboxylate, 96%


Overview
Brand: Alfa Aesar™

Manufacturer Part Number: A10933.30

DIETHYL ACETONE-1,3-DICARBOXYLATE, 96%,250G

UNSPSC: 12352106

Code: NEW

Additional Details:
Additional Details: CAS Number: 105-50-0 Weight: 0.01000kg


Quantity 250g

Product Code. 11414343

Quantity Price
1 £ 59.89 / 250g
Estimated Shipment date
from Supplier 07-12-2016
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Description and Specification

Chemical Identifiers

Chemical Name or Material Diethyl acetone-1,3-dicarboxylate
CAS 105-50-0
Molecular Formula C9H14O5
Formula Weight 202.21g/mol
MDL Number MFCD00009200
Beilstein 640146
Synonym Acetone-1,3-dicarboxylic acid diethyl ester; Diethyl 3-oxoglutarate

Specification

Quantity 250g
Boiling Point 134° to 135°C (10mmHg)
Flash Point 86°C (186°F)
Quantity 250g
Chemical Name or Material Diethyl acetone-1,3-dicarboxylate
CAS 105-50-0
Assay 96%
Molecular Formula C9H14O5
Formula Weight 202.21g/mol
MDL Number MFCD00009200
Beilstein 640146
Synonym Acetone-1,3-dicarboxylic acid diethyl ester; Diethyl 3-oxoglutarate
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H227
Combustible liquid.
Health Hazard 3 GHS P Statement
P210-P280-P370+P378a-P403+P235-P501a
Keep away from heat/sparks/open flames/hot surfaces.
- No smoking.
Wear protective gloves/protective clothing/eye protection/face protection.
In case of fire: Use for extinction: CO2, powder or water spray.
Store in a well-ventilated place.
Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Recommended Storage 2°C to 8°C
TSCA TSCA

Applications
Synthesis of 1-substituted 4-ethoxycarbonyl-5- (ethoxycarbonylmethyl) pyrazoles Diethyl acetone-1, 3-dicarboxylate reacts with N, N-dimethylforma- mide dimethyl acetal (DMFDMA) in ethanol at room temperature. Unexpected product dichotomy is produced in the Biginelli-like condensation of 2-hydroxybenzaldehyde with urea or thiourea and dimethyl or diethyl acetone-1,3-dicarboxylate, respectively, as active methylene components. Ethyl 2-amino-4-(2-ethoxy-2-oxoethyl)thiazole-5-carboxylate (2a), prepared from diethylacetone-1,3-dicarboxylate, sulfuryl chloride and thiourea. Synthesis of diethyl 2,2-diethyl-3,5-dioxopimelate by the reaction of ethyl 3-chloro-3-oxo-2,2-dimethylpropionate with diethyl acetone-1,3-dicarboxylate.

Solubility
Insoluble in water and soluble in alcohol, ester, benzene.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Safety and Handling

Warning

GHS H Statement
H227
Combustible liquid.

GHS P Statement
P210-P280-P370+P378a-P403+P235-P501a
Keep away from heat/sparks/open flames/hot surfaces.
- No smoking.
Wear protective gloves/protective clothing/eye protection/face protection.
In case of fire: Use for extinction: CO2, powder or water spray.
Store in a well-ventilated place.
Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.

2°C to 8°C