Di-tert-butylchlorophosphine, 96%

Product Code.	Quantity	unitSize
11325349	5 g	5g
11315349	1 g	1g
11335349	25 g	25g

Product Code. 11325349 Supplier Thermo Scientific Alfa Aesar Supplier No. B20998.06

Description

CAS: 13716-10-4 | C8H18ClP | 180.656 g/mol

Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

Solubility
Miscible with terahydrofuran.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.

Tekniske data

Kemiske identifikatorer

• CAS: 13716-10-4
• Molecular Formula: C8H18ClP
• Molecular Weight (g/mol): 180.656
• MDL Number: MFCD00008815
• InChI Key: MCRSZLVSRGTMIH-UHFFFAOYSA-N
• Synonym: di-tert-butylchlorophosphine, di-tert-butylchlorophosphane, di-t-butylchlorophosphine, phosphinous chloride, bis 1,1-dimethylethyl, chlorodi-tert-butylphosphine, phosphinous chloride, di-tert-butyl, di-tert-butyl chloro phosphane, di-tert-butylphosphinous chloride, clptbu2, pubchem6477
• PubChem CID: 139566
• IUPAC Name: ditert-butyl(chloro)phosphane
• SMILES: CC(C)(C)P(C(C)(C)C)Cl

• Density: 0.951
• Boiling Point: 47°C to 49°C (3 mmHg)
• Flash Point: 62°C (144°F)
• Odor: Acrid
• Linear Formula: [(CH₃)₃C]₂PCl
• Refractive Index: 1.484
• Quantity: 5 g
• UN Number: UN3265
• Sensitivity: Air and moisture sensitive
• Solubility Information: Miscible with terahydrofuran.
• Formula Weight: 180.66
• Percent Purity: 96%
• Chemical Name or Material: Di-tert-butylchlorophosphine

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