Alfa Aesar™ Dess-Martin periodinane


Overview
Brand: Alfa Aesar™

Manufacturer Part Number: L15779.03

UNSPSC: 12352101

Code: NEW

Additional Details:
Additional Details: CAS Number: 87413-09-0 Weight: 0.01000kg


Quantity 1g

Product Code. 11362777

Quantity Price
1 £ 21.62 / 1g
Estimated Shipment date
from Supplier 08-05-2017
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Description and Specification

Chemical Identifiers

Chemical Name or Material Dess-Martin periodinane
CAS 87413-09-0
Molecular Formula C13H13IO8
Formula Weight 424.15
MDL Number MFCD00130127
UN Number UN1479
Beilstein 4548207
Merck Index 14,2933
Synonym DMP; 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one

Specification

Formula Weight 424.15
Molecular Formula C13H13IO8
Melting Point 130° to 132°C
Quantity 1g
Health Hazard 3 GHS P Statement
P221-P210-P220-P305+P351+P338-P405-P501a
Take any precaution to avoid mixing with combustibles.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Keep/Store away from clothing/combustible materials.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Beilstein 4548207
UN Number UN1479
Recommended Storage −30° to −10°C
Health Hazard 1 Danger
Chemical Name or Material Dess-Martin periodinane
Synonym DMP; 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one
Health Hazard 2 GHS H Statement
H272-H315-H319-H335
May intensify fire; oxidizer.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
MDL Number MFCD00130127
Merck Index 14,2933
DOT Information Transport Hazard Class: 5.1; Packing Group: III; Proper Shipping Name: OXIDIZING SOLID, N.O.S.
CAS 87413-09-0

Applications
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

Solubility
Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.

Notes
Store in cool place. Air and moisture sensitive. Incompatible with strong reducing agents, combustible material and water.

Documentation

Technical documents

Safety and Handling

Danger

GHS H Statement
H272-H315-H319-H335
May intensify fire; oxidizer.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

GHS P Statement
P221-P210-P220-P305+P351+P338-P405-P501a
Take any precaution to avoid mixing with combustibles.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Keep/Store away from clothing/combustible materials.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

−30° to −10°C