Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%

Product Code.	Quantity	Unit Size
11327537	0.25 g	0.25g
11307537	1 g	1g
11317537	5 g	5g

Product Code. 11327537 Supplier Thermo Scientific Alfa Aesar Supplier No. 012749.01

Description

CAS: 12112-67-3 | C16H24Cl2Ir2 | 671.70 g/mol

Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 12112-67-3
• Molecular Formula: C16H24Cl2Ir2
• Molecular Weight (g/mol): 671.70
• MDL Number: MFCD00012414
• InChI Key: ZFOUDQNHNLDNLD-MIXQCLKLSA-L
• Synonym: chloro 1,5-cyclooctadiene iridium i dimer, bis 1,5-cyclooctadiene diiridium i dichloride, 1z,5z-cycloocta-1,5-diene; iridium; dichloride, iridium, di-.mu.-chlorobis 1,2,5,6-.eta.-1,5-cyclooctadiene di, ir2cl2 cod 2, chloro-1,5-cyclooctadiene iridium i dimer, 1z,5z-cycloocta-1,5-diene; iridium 1+
• PubChem CID: 6436381
• IUPAC Name: (1Z,5Z)-cycloocta-1,5-diene;iridium;dichloride
• SMILES: [Cl-].[Cl-].[Ir+].[Ir+].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1

• Melting Point: 190°C (decomposition)
• Color: White
• Odor: Odorless
• Quantity: 0.25 g
• Solubility Information: Soluble in chloroform and toluene. Slightly soluble in acetone and alcohol. Insoluble in water.
• Formula Weight: 671.71
• Physical Form: Crystalline Powder
• Chemical Name or Material: Chloro(1, 5-cyclooctadiene)iridium(I) dimer

Safety and Handling

Product Identifier

• Chloro(1,5-cyclooctadiene)iridium(I) dimer

Mention d'avertissement

• Warning

Catégorie de danger

• Serious eye damage/eye irritation Category 2
• Skin corrosion/irritation Category 2
• Specific target organ toxicity Category 3

Mention de danger

• H315-Causes skin irritation.
• H319-Causes serious eye irritation.
• H335-May cause respiratory irritation.

Conseils de prudence

• P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P302+P352-IF ON SKIN: Wash with plenty of water/soap.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Informations supplémentaires

• MIXTURE LIST-Contain: Chloro(1,5-cyclooctadiene)iridium(I) dimer

FDS

RUO – Research Use Only