Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)

Product Code.	Quantity	unitSize
15496635	1 g	1g
15406645	5 g	5g
15416645	25 g	25g

Product Code. 15496635 Supplier Thermo Scientific Alfa Aesar Supplier No. 044955.03

Beskrivelse

CAS: 16971-33-8 | C55H46ClOP3Ru | 952.41 g/mol

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is used as a raw material to synthesize other ru-hydride catalysts. It is involved in the hydrogenation of ring-opening metathesis polymers such as norbornene and other cyclic olefin ROMP polymers used as plastics, resins and optical materials. It can act as an alternative catalyst to rhodium hydrogenation catalyst. It also serves as a catalyst in the hydrogenation of conjugated diene copolymers like acrylonitrile-butadiene rubber (NBR).

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Tekniske data

Kemiske identifikatorer

• CAS: 16971-33-8
• Molecular Formula: C55H46ClOP3Ru
• Molecular Weight (g/mol): 952.41
• MDL Number: MFCD00049804
• InChI Key: IMPHYUNMDWWJAH-UHFFFAOYSA-M
• Synonym: carbonylchlorohydridotris triphenylphosphine-ruthenium ii
• PubChem CID: 71463878
• IUPAC Name: formaldehyde;hydride;ruthenium(2+);triphenylphosphane;chloride
• SMILES: Cl[RuH++].[C-]#[O+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1

• Melting Point: 204°C to 206°C (decomposition)
• Color: Gray
• Linear Formula: [(C₆H₅)₃P]₃Ru(CO)(Cl)H
• Quantity: 1 g
• Sensitivity: Light sensitive; Very Hygroscopic
• Solubility Information: Insoluble in water,ethanol,and DMSO. Sparingly soluble in benzene,chloroform and acetone.
• Formula Weight: 952.41
• Physical Form: Crystalline
• Chemical Name or Material: Carbonylchlorohydridotris (triphenylphosphine)ruthenium (II)

Sikkerhed og håndtering

Produktidentifikator

• Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)

Signalord

• Warning

Farekategori

• Acute toxicity Category 4
• Serious eye damage/eye irritation Category 2
• Skin corrosion/irritation Category 2
• Specific target organ toxicity Category 3

Faresætning

• H302-Harmful if swallowed.
• H312-Harmful in contact with skin.
• H315-Causes skin irritation.
• H319-Causes serious eye irritation.
• H332-Harmful if inhaled.
• H335-May cause respiratory irritation.

Sikkerhedssætning

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P302+P352-IF ON SKIN: Wash with plenty of water/soap.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P312-Call a POISON CENTER/doctor/if you feel unwell.

Supplerende oplysninger

• MIXTURE LIST-Contain: Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)

SDS

RUO – Research Use Only