Bis(triphenylphosphoranylidene)ammonium chloride, 97% (dry wt.), water <3%

Codice prodotto. 11393476

Marca: Thermo Scientific Alfa Aesar L14339.06

Descrizione

CAS: 21050-13-5 | C36H30ClNP2 | 574.04 g/mol

Co-catalyst used with a chiral Cobalt-salen complex for the asymmetric addition of carbon dioxide to propylene oxide. Also used in the preparation of 5-Hydroxy-clethodim Sulfoxide.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Co-catalyst used with a chiral Cobalt-salen complex for the asymmetric addition of carbon dioxide to propylene oxide. Also used in the preparation of 5-Hydroxy-clethodim Sulfoxide.

Solubility
Moderately soluble in water.

Notes
Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Specifica

Identificatori chimici

• CAS: 21050-13-5
• Molecular Formula: C36H30ClNP2
• Molecular Weight (g/mol): 574.04
• MDL Number: MFCD00151523
• InChI Key: LVRCYPYRKNAAMX-UHFFFAOYSA-M
• Synonym: 1,1,1-triphenyl-n-triphenylphosphoranylidene phosphoraniminium chloride, bis triphenylphosphoranylidene ammonium chloride, bis triphenylphosphoranylidene ammonium, triphenyl p,p,p-triphenylphosphine imidato-n phosphorus 1+ tetracarbonylcobaltate 1-, bis triphenylphosphine iminium chloride∼ppncl, ppn chloride, ppn cl, ksc491c1r, parent, triphenyl p,p,p-triphenylphosphine imidato phosphorus 1+ chloride
• PubChem CID: 3036656
• IUPAC Name: triphenyl-[(triphenyl-$l^{5}-phosphanylidene)amino]phosphanium;chloride
• SMILES: [Cl-].C1=CC=C(C=C1)P(=[N+]=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1

• Melting Point: 274°C to 276°C
• Quantity: 5 g
• Beilstein: 4097979
• Solubility Information: Moderately soluble in water.
• Formula Weight: 574.05
• Percent Purity: 97%
• Assay: (dry wt.), water <3%
• Chemical Name or Material: Bis(triphenylphosphoranylidene)ammonium chloride

Sicurezza e movimentazione

Identificativo prodotto

• Bis(triphenylphosphoranylidene)ammoniumchloride

Avvertenza

• Warning

Categoria di pericolo

• Serious eye damage/eye irritation Category 2
• Skin corrosion/irritation Category 2
• Specific target organ toxicity Category 3

Indicazioni di pericolo

• H315-Causes skin irritation.
• H319-Causes serious eye irritation.
• H335-May cause respiratory irritation.

Consigli di prudenza

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P302+P352-IF ON SKIN: Wash with plenty of water/soap.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P312-Call a POISON CENTER/doctor/if you feel unwell.
• P332+P313-If skin irritation occurs: Get medical advice/attention.
• P337+P313-If eye irritation persists: Get medical advice/attention.

Informazioni supplementari

• MIXTURE LIST-Contains : Bis(triphenylphosphoranylidene)ammoniumchloride

SDS

RUO – Research Use Only