Alfa Aesar™ Bis(pentafluorophenyl)phenylphosphine, 97%


Overview
Brand: Alfa Aesar™

Manufacturer Part Number: A11014-03

BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE,1G

UNSPSC: 12352128

Code: NEW

Additional Details:
Additional Details: CAS Number: 5074-71-5 Weight: 0.01000kg


Quantity 1g

Product Code. 11414493

Quantity Price
1 £ 106.74 / 1g
Estimated Shipment date
from Supplier 02-01-2017
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Description and Specification

Chemical Identifiers

Chemical Name or Material Bis (pentafluorophenyl)phenylphosphine
CAS 5074-71-5
Molecular Formula C18H5F10P
Formula Weight 442.20g/mol
MDL Number MFCD00000291
Beilstein 6253897
Synonym Decafluorotriphenylphosphine; Phenylbis(pentafluorophenyl)phosphine

Specification

Melting Point 59° to 64°C
Boiling Point 105°C (0.3mmHg)
Quantity 1g
Flash Point >110°C (230°F)
Chemical Name or Material Bis (pentafluorophenyl)phenylphosphine
CAS 5074-71-5
Assay 97%
Molecular Formula C18H5F10P
Formula Weight 442.20g/mol
MDL Number MFCD00000291
Beilstein 6253897
Synonym Decafluorotriphenylphosphine; Phenylbis(pentafluorophenyl)phosphine
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Applications
Bis(pentafluorophenyl)phenylphosphine is used as a ligand involved in the palladium-catalyzed Heck reaction of iodobenzene and styrene in compressed carbon dioxide. It is also used in the polymerization of 1,3-butadiene with Co(2-ethyl hexanoate)2.

Solubility
Soluble in chloroform, dichloromethane, tetrahydrofuran, benzene, toluene, ethanol, methanol, and supercritical carbon dioxide.

Notes
Store in a cool place. Incompatible with strong oxidizing agents, strong reducing agents, strong acids and bases.

Safety and Handling

Warning

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.