Allylmagnesium bromide, 1M solution in diethyl ether, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10081544	Thermo Scientific Acros 209531000	100 mL	AcroSeal™ Glass bottle
10735135	Thermo Scientific Acros 209538000	800 mL	AcroSeal™ Glass bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 1730-25-2
• Molecular Weight (g/mol): 145.28
• InChI Key: FEMBXICCJNZMMC-UHFFFAOYSA-M
• PubChem CID: 74413
• SMILES: Br[Mg]CC=C

• Molecular Formula: C3H5BrMg
• MDL Number: MFCD00000044
• Synonym: allylmagnesium bromide, allyl magnesium bromide, allylmagnesium bromide solution, sjpdabpprujp@, allylmagnesium bromide solution, 1.0 m in diethyl ether, allylmagnesiumbromid, allylmagnesiumbromide, allyl magnesiumbromide, allyl-magnesium bromide, 2-propenylmagnesium bromide, grignard reagent
• IUPAC Name: magnesium;prop-1-ene;bromide

Specifications

• CAS: 1730-25-2
• CAS Max %: 18.78, 84.64
• Density: 0.8510g/mL
• Molecular Formula: C3H5BrMg
• MDL Number: MFCD00000044
• Specific Gravity: 0.851
• InChI Key: FEMBXICCJNZMMC-UHFFFAOYSA-M
• IUPAC Name: magnesium;prop-1-ene;bromide
• PubChem CID: 74413
• Physical Form: Solution

• CAS Min %: 15.37, 81.22
• Color: Gray or Green-Yellow
• Flash Point: −40°C
• Linear Formula: H₂C=CHCH₂MgBr
• UN Number: 3399
• Synonym: allylmagnesium bromide, allyl magnesium bromide, allylmagnesium bromide solution, sjpdabpprujp@, allylmagnesium bromide solution, 1.0 m in diethyl ether, allylmagnesiumbromid, allylmagnesiumbromide, allyl magnesiumbromide, allyl-magnesium bromide, 2-propenylmagnesium bromide, grignard reagent
• SMILES: Br[Mg]CC=C
• Molecular Weight (g/mol): 145.28
• Formula Weight: 145.28
• Chemical Name or Material: Allylmagnesium bromide, 1M solution in diethyl ether

Safety and Handling

GHS H Statement
Extremely flammable liquid and vapor.
Catches fire spontaneously if exposed to air.
In contact with water releases flammable gases which may ignite spontaneously.
Harmful if swallowed.
Causes severe skin bur

GHS P Statement
Wear protective gloves/protective clothing/eye protection/face protection.
IF SWALLOWED: Rinse mouth.
Do NOT induce vomiting.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses,if pre

GHS Signal Word: Danger

missing translation for 'einecsNumber' : 217-046-4

Product Identifier

• Allylmagnesium bromide, 1M solution in diethylether

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 1
• Pyrophoric liquid Category 1
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H336-May cause drowsiness or dizziness.
• H302-Harmful if swallowed.
• H250-Catches fire spontaneously if exposed to air.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H224-Extremely flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.
• EUH066-Repeated exposure may cause skin dryness or cracking.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P231+P232-Handle under inert gas. Protect from moisture.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only