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Alfa Aesar™ 3-Phenylpropionyl chloride, 98%

Brand:  Alfa Aesar™ A10860.30

Code : NEW

Additional Details : CAS Number : 645-45-4 Weight : 0.25000kg Transport : UN number : 3265 Chem class : 1a Pack group : II

Quantity 250g

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Product Code. 11469842

  • £434.60 / 250g


Estimated Shipment date
from Supplier 31-10-2017
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Description

Description

Applications
The 3-phenylpropionate (dihydrocinnamoyl) ester has been used as a protecting group in nucleoside synthesis. Used in the synthesis of 1-Phenyl-3-methyl-4-acyl-5- pyrazolones. N-(3-phenyl-n-propyl)-1-phenyl-2-aminopropane were prepared by acylation of the appropriate amine with 3-phenylpropionyl chloride followed by reduction of the resulting amide with either LiA1H4. For the preparation of the phenylacetyl (PA) and 3-phenylpropionyl (PP) derivatives, the corresponding amino acids were coupled in the usual manner with phenylacetyl chloride or 3-phenylpropionyl chloride in the presence of either NaOH(PA-LD- and DL-Pgly. 3-Phenylpropionyl chloride (4) was treated with diazomethane to give diazoketone. Allyloxy resin 12 was acylated with 3-phenylpropionyl chloride and treated with 50% TFA for 1 h followed by treatment with Pd(PPh3)4/PPh3 in solution to furnish the desired hydrox- amic acid.

Notes
Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, amines, alcohols, active metals, bases, water, moisture.
Specifications

Chemical Identifiers

3-Phenylpropionyl chloride
C6H5(CH2)2COCl
MFCD00000748
742586
645-45-4
168.62
UN3265
Hydrocinnamoyl chloride

Specifications

3-Phenylpropionyl chloride
645-45-4
98%
168.62
UN3265
Hydrocinnamoyl chloride
−7°C
250g
Acrid
C6H5(CH2)2COCl
MFCD00000748
742586
225°C
108°C (226°F)
Documentation

Technical Documents