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Alfa Aesar™ 3-Bromocyclohexene, 95%, stab. with 300-1000ppm Propylene oxide

Brand:  Alfa Aesar™ A10370.22

Code : NEW

Additional Details : CAS Number : 1521-51-3 Weight : 0.10000kg Transport : UN number : 1993 Chem class : 1 Pack group : III

Quantity 100g

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Product Code. 11454183

  • £353.50 / 100g


Estimated Shipment date
from Supplier 08-12-2017
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Description

Description

Applications
In peptide synthesis, can be used to protect the hydroxyl group of serine and threonine as the cyclohexyl (Chx) ether, by reaction with the sodium alkoxide (generated with NaH), followed by hydrogenation. The group is stable to TFA and 20% piperidine in DMF, but can be cleaved with TfOH in TFA, in the presence of thioanisole as a cation scavenger. It is also used in the synthesis of N-tert-butoxycarbonyl-O-cyclohexyl-L-tyrosine.1 It was also used in the synthesis of enantiopure cyclohexitols such as muco-quercitol, D-chiro-inocitol and allo-inocitol.

Solubility
Not miscible or difficult to mix in water.

Notes
Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
Specifications

Chemical Identifiers

3-Bromocyclohexene
Stabilized with 300 to 1000ppm Propylene oxide
161.05
UN1993
2-Cyclohexenyl bromide
1521-51-3
C6H9Br
MFCD00013775
635953

Specifications

3-Bromocyclohexene
1521-51-3
C6H9Br
MFCD00013775
635953
64° to 65°C (15mmHg)
54°C (129°F)
Stabilized with 300 to 1000ppm Propylene oxide
95%
161.05
UN1993
2-Cyclohexenyl bromide
100g
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