2-Methylanisole, 99%

Artikelnummer.	Quantity	Packungsgröße
11491598	50 g	50g
11401608	250 g	250g
11481598	1000 g	1000g

Artikelnummer. 11491598 Lieferant Thermo Scientific Alfa Aesar Lieferanten-Nr. A13897.18

Beschreibung

CAS: 578-58-5 | C8H10O | 122.167 g/mol

The catalytic system of disubstituted aromatics was optimized for the 2-methylanisole reduction by a proper choice of the amine/Rh ratio which should be high enough to stabilize very small colloidal rhodium particles and low enough to avoid deactivation. The total synthesis of (±)-heliannuol D and its epimer has been completed in 9 steps and 12% overall yield from 2-methylanisole. The thermal activation of 2-methylanisole (60°C) by the Ir (III) complex TpMe2Ir (C6H5) 2 (N2)(1; TpMe2= hydrotris (3, 5-dimethylpyrazolyl) borate) yielded a mixture of hydride complexes. The total synthesis of the phenolic sesquiterpene mutisianthol has been accomplished in 12 steps from the readily available 2-methylanisole. The catalytic system was optimized for the 2-methylanisole reduction by a proper choice of the amine/Rh ratio which should be high enough to stabilize very small colloidal rhodium particles and low enough to avoid deactivation.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
The catalytic system of disubstituted aromatics was optimized for the 2-methylanisole reduction by a proper choice of the amine/Rh ratio which should be high enough to stabilize very small colloidal rhodium particles and low enough to avoid deactivation. The total synthesis of (±)-heliannuol D and its epimer has been completed in 9 steps and 12% overall yield from 2-methylanisole. The thermal activation of 2-methylanisole (60°C) by the Ir (III) complex TpMe2Ir (C6H5) 2 (N2)(1; TpMe2= hydrotris (3, 5-dimethylpyrazolyl) borate) yielded a mixture of hydride complexes. The total synthesis of the phenolic sesquiterpene mutisianthol has been accomplished in 12 steps from the readily available 2-methylanisole. The catalytic system was optimized for the 2-methylanisole reduction by a proper choice of the amine/Rh ratio which should be high enough to stabilize very small colloidal rhodium particles and low enough to avoid deactivation.

Solubility
Insoluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Spezifikation

Chemische Identifikatoren

• CAS: 578-58-5
• Molecular Formula: C8H10O
• Molecular Weight (g/mol): 122.167
• MDL Number: MFCD00008373
• InChI Key: DTFKRVXLBCAIOZ-UHFFFAOYSA-N
• Synonym: 2-methylanisole, o-methylanisole, 2-methoxytoluene, o-cresol methyl ether, o-cresyl methyl ether, anisole, o-methyl, benzene, 1-methoxy-2-methyl, methyl o-tolyl ether, o-methoxytoluene, 2-methylmethoxybenzene
• PubChem CID: 33637
• IUPAC Name: 1-methoxy-2-methylbenzene
• SMILES: CC1=CC=CC=C1OC

• Density: 0.985
• Boiling Point: 170°C to 172°C
• Flash Point: 51°C (123°F)
• Refractive Index: 1.517
• Quantity: 50 g
• UN Number: UN3271
• Beilstein: 1857415
• Solubility Information: Insoluble in water.
• Formula Weight: 122.17
• Percent Purity: 99%
• Chemical Name or Material: 2-Methylanisole

Sicherheit und Handhabung

Produktidentifikator

• 2-Methylanisole

Signalwort

• Warning

Gefahrenkategorie

• Flammable liquid Category 3

Gefahrenhinweis

• H226-Flammable liquid and vapour.

Sicherheitshinweis

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Ergänzende Informationen

• MIXTURE LIST-Contain: 2-Methylanisole

Sicherheitsdatenblatt (SDS)

RUO – Research Use Only