1-Bromo-4-iodobenzene, 98%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11401528	Thermo Scientific Alfa Aesar A13859.09	10 g
11411528	Thermo Scientific Alfa Aesar A13859.18	50 g
11421528	Thermo Scientific Alfa Aesar A13859.30	250 g

Description

It is mainly used as the OLED pharmaceutical intermediate, as reagent for in situ desilylation and coupling of silylated alkynes, as substrate in copper-free Sonogashira coupling in aqueous acetone. It is also used in synthesis of β,β,dibromostyrenes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids).

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is mainly used as the OLED pharmaceutical intermediate, as reagent for in situ desilylation and coupling of silylated alkynes, as substrate in copper-free Sonogashira coupling in aqueous acetone. It is also used in synthesis of β,β,dibromostyrenes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids).

Solubility
Insoluble in water.

Notes
Light sensitive. Store in a cool, dry, well-ventilated area. Store away from oxidizing agent, light.

Chemical Identifiers

• CAS: 589-87-7
• Molecular Weight (g/mol): 282.906
• InChI Key: UCCUXODGPMAHRL-UHFFFAOYSA-N
• PubChem CID: 11522
• SMILES: C1=CC(=CC=C1Br)I

• Molecular Formula: C6H4BrI
• MDL Number: MFCD00001051
• Synonym: 4-bromoiodobenzene, benzene, 1-bromo-4-iodo, p-bromoiodobenzene, p-iodobromobenzene, p-bromophenyl iodide, 4-bromo-1-iodobenzene, 1-bromo-4-iodo-benzene, 4-iodobromobenzene, rarechem fh 1g 0a12, p-bromo iodobenzene
• IUPAC Name: 1-bromo-4-iodobenzene

Specifications

• CAS: 589-87-7
• Boiling Point: 252°C
• Odor: Recognizable
• MDL Number: MFCD00001051
• Sensitivity: Light sensitive
• Solubility Information: Insoluble in water.
• SMILES: C1=CC(=CC=C1Br)I
• Molecular Weight (g/mol): 282.906
• Formula Weight: 282.91
• Chemical Name or Material: 1-Bromo-4-iodobenzene

• Melting Point: 89°C to 93°C
• Assay Percent Range: 98%
• Molecular Formula: C6H4BrI
• Beilstein: 1904545
• Synonym: 4-bromoiodobenzene, benzene, 1-bromo-4-iodo, p-bromoiodobenzene, p-iodobromobenzene, p-bromophenyl iodide, 4-bromo-1-iodobenzene, 1-bromo-4-iodo-benzene, 4-iodobromobenzene, rarechem fh 1g 0a12, p-bromo iodobenzene
• InChI Key: UCCUXODGPMAHRL-UHFFFAOYSA-N
• IUPAC Name: 1-bromo-4-iodobenzene
• PubChem CID: 11522
• Percent Purity: 98%

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

missing translation for 'einecsNumber' : 209-662-7

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures

RUO – Research Use Only