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1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%

Product Code. 11359717
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Quantity:
250 mg
Unit Size:
250mg
Product Code. Quantity unitSize
11359717 250 mg 250mg
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Product Code. 11359717

Brand: Thermo Scientific Alfa Aesar 042057.MD

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Description

CAS: 64536-78-3 | C31H50F6IrNP2 | 804.90 g/mol

1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

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Specifications

CAS 64536-78-3
Melting Point 175°C (decomposition)
Molecular Formula C31H50F6IrNP2
MDL Number MFCD00075097
Quantity 250 mg
Sensitivity Moisture sensitive
Synonym crabtree's catalyst, unii-816rs2nbpn, 816rs2nbpn, 1,5-cyclooctadiene pyridine tricyclohexylphosphine iridium hexafluorophosphate, iridium i hexafluorophosphate, 1,5-cyclooctadiene pyridine tricyclohexylphosphine iridium i hexafluorophosphate, tricyclohexylphosphine 1,5-cyclooctadiene pyridine iridium i hexafluorophosphate, felkin-crabtree catalyst, crabtree's catalyst mi, crabtree's catalyst hexafluorophosphate
Solubility Information Slightly soluble in acetone,dichloromethane,ethanol and diethyl ether; Insoluble in water.
InChI Key UJXHUUQZACSUOG-KJWGIZLLSA-N
SMILES [Ir+].C1=CC=NC=C1.F[P-](F)(F)(F)(F)F.C1C\C=C/CC\C=C/1.C1CCC(CC1)P(C1CCCCC1)C1CCCCC1
IUPAC Name (1Z,5Z)-cycloocta-1,5-diene;iridium;pyridine;tricyclohexylphosphane;hexafluorophosphate
Molecular Weight (g/mol) 804.90
PubChem CID 5702647
Formula Weight 804.89
Percent Purity 99%
Physical Form Crystalline Powder
Chemical Name or Material 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate
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