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Aminosaccharides

Monosaccharides in which a single hydroxy group has been replaced by an amino group; components of structural polysaccharides and glycosphingolipids; important in the formation of lipids, proteins, insect exoskeletons, and plant cell walls.

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1

Tylvalosin (>90%), TRC

CAS: 63409-12-1 Molecular Formula: C53 H87 N O19 Molecular Weight (g/mol): 1042.25 Synonym: Tylosin, 3-acetate 4B-(3-methylbutanoate),Oxacyclohexadecane, tylosin deriv.,3-O-Acetyl-4' '-O-isovaleryltylosin,Acetylisovaleryltylosin,Tylvalosin IUPAC Name: [(2S,3S,4R,6S)-6-[(2R,3S,4R,5R,6R)-6-[[(4R,5S,6S,7R,9R,11E,13E,15R,16R)-4-acetyloxy-16-ethyl-15-[[(2R,3R,4R,5R,6R)-5-hydroxy-3,4-dimethoxy-6-methyloxan-2-yl]oxymethyl]-5,9,13-trimethyl-2,10-dioxo-7-(2-oxoethyl)-1-oxacyclohexadeca-11,13-dien-6-yl]oxy]-4-(dimethylamino)-5-hydroxy-2-methyloxan-3-yl]oxy-4-hydroxy-2,4-dimethyloxan-3-yl] 3-methylbutanoate SMILES: CC[C@H]1OC(=O)C[C@@H](OC(=O)C)[C@H](C)[C@@H](O[C@@H]2O[C@H](C)[C@@H](O[C@H]3C[C@@](C)(O)[C@@H](OC(=O)CC(C)C)[C@H](C)O3)[C@@H]([C@H]2O)N(C)C)[C@@H](CC=O)C[C@@H](C)C(=O)\C=C\C(=C\[C@@H]1CO[C@@H]4O[C@H](C)[C@@H](O)[C@@H](OC)[C@H]4OC)\C

CAS 63409-12-1
Molecular Weight (g/mol) 1042.25
SMILES CC[C@H]1OC(=O)C[C@@H](OC(=O)C)[C@H](C)[C@@H](O[C@@H]2O[C@H](C)[C@@H](O[C@H]3C[C@@](C)(O)[C@@H](OC(=O)CC(C)C)[C@H](C)O3)[C@@H]([C@H]2O)N(C)C)[C@@H](CC=O)C[C@@H](C)C(=O)\C=C\C(=C\[C@@H]1CO[C@@H]4O[C@H](C)[C@@H](O)[C@@H](OC)[C@H]4OC)\C
Synonym Tylosin, 3-acetate 4B-(3-methylbutanoate),Oxacyclohexadecane, tylosin deriv.,3-O-Acetyl-4' '-O-isovaleryltylosin,Acetylisovaleryltylosin,Tylvalosin
IUPAC Name [(2S,3S,4R,6S)-6-[(2R,3S,4R,5R,6R)-6-[[(4R,5S,6S,7R,9R,11E,13E,15R,16R)-4-acetyloxy-16-ethyl-15-[[(2R,3R,4R,5R,6R)-5-hydroxy-3,4-dimethoxy-6-methyloxan-2-yl]oxymethyl]-5,9,13-trimethyl-2,10-dioxo-7-(2-oxoethyl)-1-oxacyclohexadeca-11,13-dien-6-yl]oxy]-4-(dimethylamino)-5-hydroxy-2-methyloxan-3-yl]oxy-4-hydroxy-2,4-dimethyloxan-3-yl] 3-methylbutanoate
Molecular Formula C53 H87 N O19
2

Emamectin Benzoate (90%), TRC

CAS: 155569-91-8 Molecular Formula: C49 H75 N O13 . C48 H73 N O13 . 2 C7 H6 O2 Molecular Weight (g/mol): 2002.45 Synonym: Avermectin B1, 4' '-deoxy-4' '-(methylamino)-, (4' 'R)-, benzoate (1:1),Avermectin B1, 4' '-deoxy-4' '-(methylamino)-, (4' 'R)-, benzoate (salt) (9CI),(4' 'R)-4' '-Deoxy-4' '-(methylamino)avermectin B1 benzoate,Affirm,Denim,Denim (pesticide),Emamectin benzoate,Emamectin benzoate (salt),MK 244,Methylamino abamectin benzoate,Proclaim,Proclaim 05SG,Proclaim 5SG,Revive,Revive (insecticide),Sch 58854,Shot Wan Liquid Formulation,Shot-Wan,Slice,Tree-age SMILES: CC[C@H](C)[C@H]1O[C@@]2(C[C@@H]3C[C@@H](C\C=C(/C)\[C@@H](O[C@H]4C[C@H](OC)[C@@H](O[C@H]5C[C@H](OC)[C@H](NC)[C@H](C)O5)[C@H](C)O4)[C@@H](C)\C=C\C=C\6/CO[C@@H]7[C@H](O)C(=C[C@@H](C(=O)O3)[C@]67O)C)O2)C=C[C@@H]1C.CN[C@@H]8[C@H](C)O[C@H](C[C@@H]8OC)O[C@H]9[C@H](C)O[C@H](C[C@@H]9OC)O[C@H]%10[C@@H](C)\C=C\C=C\%11/CO[C@@H]%12[C@H](O)C(=C[C@@H](C(=O)O[C@H]%13C[C@@H](C\C=C\%10/C)O[C@@]%14(C%13)O[C@H](C(C)C)[C@@H](C)C=C%14)[C@]%11%12O)C.OC(=O)c%15ccccc%15.OC(=O)c%16ccccc%16

CAS 155569-91-8
Molecular Weight (g/mol) 2002.45
SMILES CC[C@H](C)[C@H]1O[C@@]2(C[C@@H]3C[C@@H](C\C=C(/C)\[C@@H](O[C@H]4C[C@H](OC)[C@@H](O[C@H]5C[C@H](OC)[C@H](NC)[C@H](C)O5)[C@H](C)O4)[C@@H](C)\C=C\C=C\6/CO[C@@H]7[C@H](O)C(=C[C@@H](C(=O)O3)[C@]67O)C)O2)C=C[C@@H]1C.CN[C@@H]8[C@H](C)O[C@H](C[C@@H]8OC)O[C@H]9[C@H](C)O[C@H](C[C@@H]9OC)O[C@H]%10[C@@H](C)\C=C\C=C\%11/CO[C@@H]%12[C@H](O)C(=C[C@@H](C(=O)O[C@H]%13C[C@@H](C\C=C\%10/C)O[C@@]%14(C%13)O[C@H](C(C)C)[C@@H](C)C=C%14)[C@]%11%12O)C.OC(=O)c%15ccccc%15.OC(=O)c%16ccccc%16
Synonym Avermectin B1, 4' '-deoxy-4' '-(methylamino)-, (4' 'R)-, benzoate (1:1),Avermectin B1, 4' '-deoxy-4' '-(methylamino)-, (4' 'R)-, benzoate (salt) (9CI),(4' 'R)-4' '-Deoxy-4' '-(methylamino)avermectin B1 benzoate,Affirm,Denim,Denim (pesticide),Emamectin benzoate,Emamectin benzoate (salt),MK 244,Methylamino abamectin benzoate,Proclaim,Proclaim 05SG,Proclaim 5SG,Revive,Revive (insecticide),Sch 58854,Shot Wan Liquid Formulation,Shot-Wan,Slice,Tree-age
Molecular Formula C49 H75 N O13 . C48 H73 N O13 . 2 C7 H6 O2
3

Amphotericin B Methyl Ester 90%, TRC

CAS: 36148-89-7 Molecular Formula: C49 H77 N O16 Molecular Weight (g/mol): 936.13 Synonym: Amphotericin B Monomethyl Ester; IUPAC Name: methyl (1S,3R,4E,6E,8E,10E,12E,14E,16E,18S,19R,20R,21S,25R,27R,30R,31R,33S,35R,37S,38R)-3-[(2R,3S,4S,5S,6R)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-25,27,30,31,33,35,37-heptahydroxy-18,19,20,21-tetramethyl-23-oxo-22,39-dioxabicyclo[33.3.1]nonatriaconta-4,6,8,10,12,14,16-heptaene-38-carboxylate SMILES: COC(=O)[C@@H]1[C@@H](O)C[C@@]2(O)C[C@@H](O)C[C@@H](O)[C@H](O)CC[C@@H](O)C[C@@H](O)CC(=O)O[C@@H](C)[C@H](C)[C@H](C)[C@@H](C)\C=C\C=C\C=C\C=C\C=C\C=C\C=C\[C@@H](C[C@@H]1O2)O[C@@H]3O[C@H](C)[C@@H](O)[C@H](N)[C@@H]3O

CAS 36148-89-7
Molecular Weight (g/mol) 936.13
SMILES COC(=O)[C@@H]1[C@@H](O)C[C@@]2(O)C[C@@H](O)C[C@@H](O)[C@H](O)CC[C@@H](O)C[C@@H](O)CC(=O)O[C@@H](C)[C@H](C)[C@H](C)[C@@H](C)\C=C\C=C\C=C\C=C\C=C\C=C\C=C\[C@@H](C[C@@H]1O2)O[C@@H]3O[C@H](C)[C@@H](O)[C@H](N)[C@@H]3O
Synonym Amphotericin B Monomethyl Ester;
IUPAC Name methyl (1S,3R,4E,6E,8E,10E,12E,14E,16E,18S,19R,20R,21S,25R,27R,30R,31R,33S,35R,37S,38R)-3-[(2R,3S,4S,5S,6R)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-25,27,30,31,33,35,37-heptahydroxy-18,19,20,21-tetramethyl-23-oxo-22,39-dioxabicyclo[33.3.1]nonatriaconta-4,6,8,10,12,14,16-heptaene-38-carboxylate
Molecular Formula C49 H77 N O16
4

N-Demethyl Erythromycin A (>90%), TRC

CAS: 992-62-1 Molecular Formula: C36 H65 N O13 Molecular Weight (g/mol): 719.9 Synonym: N-Demethylerythromycin A,Erythromycin Imp. B (EP),Erythromycin, N-demethyl- (6CI,7CI,8CI,9CI),Oxacyclotetradecane, erythromycin deriv.,Des-N-methylerythromycin,Desmethylerythromycin,3' '-N-Demethylerythromycin A,(3R,4S,5S,6R,7R,9R,11R,12R,13S,14R)-4-[(2,6-Dideoxy-3-C-methyl-3-O-methyl-α-L-ribo-hexopyranosyl)oxy]-14-ethyl7,12,13-trihydroxy-3,5,7,9,11,13-hexamethyl-6-[(3,4,6-trideoxy-3-methylamino-β-D-xylohexopyranosyl)oxy]oxacyclotetradecane-2,10-dione IUPAC Name: (3R,4S,5S,6R,7R,9R,11R,12R,13S,14R)-14-ethyl-7,12,13-trihydroxy-4-[(2R,4R,5S,6S)-5-hydroxy-4-methoxy-4,6-dimethyloxan-2-yl]oxy-6-[(2S,3R,4S,6R)-3-hydroxy-6-methyl-4-(methylamino)oxan-2-yl]oxy-3,5,7,9,11,13-hexamethyl-oxacyclotetradecane-2,10-dione SMILES: CC[C@H]1OC(=O)[C@H](C)[C@@H](O[C@H]2C[C@@](C)(OC)[C@@H](O)[C@H](C)O2)[C@H](C)[C@@H](O[C@@H]3O[C@H](C)C[C@H](NC)[C@H]3O)[C@](C)(O)C[C@@H](C)C(=O)[C@H](C)[C@@H](O)[C@]1(C)O

CAS 992-62-1
Molecular Weight (g/mol) 719.9
SMILES CC[C@H]1OC(=O)[C@H](C)[C@@H](O[C@H]2C[C@@](C)(OC)[C@@H](O)[C@H](C)O2)[C@H](C)[C@@H](O[C@@H]3O[C@H](C)C[C@H](NC)[C@H]3O)[C@](C)(O)C[C@@H](C)C(=O)[C@H](C)[C@@H](O)[C@]1(C)O
Synonym N-Demethylerythromycin A,Erythromycin Imp. B (EP),Erythromycin, N-demethyl- (6CI,7CI,8CI,9CI),Oxacyclotetradecane, erythromycin deriv.,Des-N-methylerythromycin,Desmethylerythromycin,3' '-N-Demethylerythromycin A,(3R,4S,5S,6R,7R,9R,11R,12R,13S,14R)-4-[(2,6-Dideoxy-3-C-methyl-3-O-methyl-α-L-ribo-hexopyranosyl)oxy]-14-ethyl7,12,13-trihydroxy-3,5,7,9,11,13-hexamethyl-6-[(3,4,6-trideoxy-3-methylamino-β-D-xylohexopyranosyl)oxy]oxacyclotetradecane-2,10-dione
IUPAC Name (3R,4S,5S,6R,7R,9R,11R,12R,13S,14R)-14-ethyl-7,12,13-trihydroxy-4-[(2R,4R,5S,6S)-5-hydroxy-4-methoxy-4,6-dimethyloxan-2-yl]oxy-6-[(2S,3R,4S,6R)-3-hydroxy-6-methyl-4-(methylamino)oxan-2-yl]oxy-3,5,7,9,11,13-hexamethyl-oxacyclotetradecane-2,10-dione
Molecular Formula C36 H65 N O13
5

12-O-Methyl Clarithromycin (>90%), TRC

CAS: 128940-83-0 Molecular Formula: C39 H71 N O13 Molecular Weight (g/mol): 761.98 Synonym: 6,12-Di-O-methylerythromycin,Oxacyclotetradecane, erythromycin deriv.,12-O-Methylclarithromycin,6,12-Di-O-methylerythromycin A,Clarithromycin Imp. F (EP) IUPAC Name: (3R,4S,5S,6R,7R,9R,11R,12R,13S,14R)-6-[(2S,3R,4S,6R)-4-(dimethylamino)-3-hydroxy-6-methyloxan-2-yl]oxy-14-ethyl-12-hydroxy-4-[(2R,4R,5S,6S)-5-hydroxy-4-methoxy-4,6-dimethyloxan-2-yl]oxy-7,13-dimethoxy-3,5,7,9,11,13-hexamethyl-oxacyclotetradecane-2,10-dione SMILES: CC[C@H]1OC(=O)[C@H](C)[C@@H](O[C@H]2C[C@@](C)(OC)[C@@H](O)[C@H](C)O2)[C@H](C)[C@@H](O[C@@H]3O[C@H](C)C[C@@H]([C@H]3O)N(C)C)[C@@](C)(C[C@@H](C)C(=O)[C@H](C)[C@@H](O)[C@]1(C)OC)OC

CAS 128940-83-0
Molecular Weight (g/mol) 761.98
SMILES CC[C@H]1OC(=O)[C@H](C)[C@@H](O[C@H]2C[C@@](C)(OC)[C@@H](O)[C@H](C)O2)[C@H](C)[C@@H](O[C@@H]3O[C@H](C)C[C@@H]([C@H]3O)N(C)C)[C@@](C)(C[C@@H](C)C(=O)[C@H](C)[C@@H](O)[C@]1(C)OC)OC
Synonym 6,12-Di-O-methylerythromycin,Oxacyclotetradecane, erythromycin deriv.,12-O-Methylclarithromycin,6,12-Di-O-methylerythromycin A,Clarithromycin Imp. F (EP)
IUPAC Name (3R,4S,5S,6R,7R,9R,11R,12R,13S,14R)-6-[(2S,3R,4S,6R)-4-(dimethylamino)-3-hydroxy-6-methyloxan-2-yl]oxy-14-ethyl-12-hydroxy-4-[(2R,4R,5S,6S)-5-hydroxy-4-methoxy-4,6-dimethyloxan-2-yl]oxy-7,13-dimethoxy-3,5,7,9,11,13-hexamethyl-oxacyclotetradecane-2,10-dione
Molecular Formula C39 H71 N O13
6

Leucomycin A3, TRC

CAS: 16846-24-5 Molecular Formula: C42 H69 N O15 Molecular Weight (g/mol): 828 Synonym: Josamycin,(4R,5S,6S,7R,9R,10R,11E,13E,16R)-4-(acetyloxy)-6-[[3,6-dideoxy-4-O-[2,6-dideoxy-3-C-methyl-4-O-(3-methylbutanoyl)-a-l-ribo-hexopyranosyl]-3-(dimethylamino)-ß-d-glucopyranosyl]oxy]-10-hydroxy-5-methoxy-9,16-dimethyl-7-(2-oxoethyl)oxacyclohexadeca-11,13-dien-2-one,Leucomycin V, 3-acetate 4B-(3-methylbutanoate),Leucomycin A3 (8CI),Oxacyclohexadecane, leucomycin V deriv.,Antibiotic YL 704A3,EN 141,Iosalide,Jomybel,Josacine,Josamina,Kitasamycin A3,Turimycin A5,Vilprafen,Wilprafen IUPAC Name: [(2S,3S,4R,6S)-6-[(2R,3S,4R,5R,6S)-6-[[(4R,5S,6S,7R,9R,10R,11E,13E,16R)-4-acetyloxy-10-hydroxy-5-methoxy-9,16-dimethyl-2-oxo-7-(2-oxoethyl)-1-oxacyclohexadeca-11,13-dien-6-yl]oxy]-4-(dimethylamino)-5-hydroxy-2-methyloxan-3-yl]oxy-4-hydroxy-2,4-dimethyloxan-3-yl] 3-methylbutanoate SMILES: CO[C@H]1[C@@H](CC(=O)O[C@H](C)C\C=C\C=C\[C@H](O)[C@H](C)C[C@H](CC=O)[C@@H]1O[C@@H]2O[C@H](C)[C@@H](O[C@H]3C[C@@](C)(O)[C@@H](OC(=O)CC(C)C)[C@H](C)O3)[C@@H]([C@H]2O)N(C)C)OC(=O)C

CAS 16846-24-5
Molecular Weight (g/mol) 828
SMILES CO[C@H]1[C@@H](CC(=O)O[C@H](C)C\C=C\C=C\[C@H](O)[C@H](C)C[C@H](CC=O)[C@@H]1O[C@@H]2O[C@H](C)[C@@H](O[C@H]3C[C@@](C)(O)[C@@H](OC(=O)CC(C)C)[C@H](C)O3)[C@@H]([C@H]2O)N(C)C)OC(=O)C
Synonym Josamycin,(4R,5S,6S,7R,9R,10R,11E,13E,16R)-4-(acetyloxy)-6-[[3,6-dideoxy-4-O-[2,6-dideoxy-3-C-methyl-4-O-(3-methylbutanoyl)-a-l-ribo-hexopyranosyl]-3-(dimethylamino)-ß-d-glucopyranosyl]oxy]-10-hydroxy-5-methoxy-9,16-dimethyl-7-(2-oxoethyl)oxacyclohexadeca-11,13-dien-2-one,Leucomycin V, 3-acetate 4B-(3-methylbutanoate),Leucomycin A3 (8CI),Oxacyclohexadecane, leucomycin V deriv.,Antibiotic YL 704A3,EN 141,Iosalide,Jomybel,Josacine,Josamina,Kitasamycin A3,Turimycin A5,Vilprafen,Wilprafen
IUPAC Name [(2S,3S,4R,6S)-6-[(2R,3S,4R,5R,6S)-6-[[(4R,5S,6S,7R,9R,10R,11E,13E,16R)-4-acetyloxy-10-hydroxy-5-methoxy-9,16-dimethyl-2-oxo-7-(2-oxoethyl)-1-oxacyclohexadeca-11,13-dien-6-yl]oxy]-4-(dimethylamino)-5-hydroxy-2-methyloxan-3-yl]oxy-4-hydroxy-2,4-dimethyloxan-3-yl] 3-methylbutanoate
Molecular Formula C42 H69 N O15