Diisobutylaluminium hydride, 1.0M solution in heptane, AcroSeal™

Description

CAS: 1191-15-7 | C₈H₁₉Al

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Lewis acid, Reduction reagent

Specifications

• Chemical Name or Material: Diisobutylaluminium hydride
• Color: Undesignated
• Name Note: 1.0M Solution in Heptane
• CAS: 1191-15-7, 142-82-5
• Melting Point: -70.0°C
• Molecular Formula: C₈H₁₉Al
• Linear Formula: [(CH₃)₂CHCH₂]₂AIH
• MDL Number: MFCD00008928
• Beilstein: 04, IV, 4400
• Concentration: 19.5 to 20.5% (DIBAL-H, on Al basis)
• Fieser: 01,260; 02,140; 03,101; 04,158; 05,224; 06,198; 07,111; 08,173; 09,171; 10,149; 11,185; 12,191; 13,115; 14,138; 15,137; 16,27; 17,123
• Density: 0.7000g/mL
• Merck Index: 15, 3212
• Synonym: DIBAL-H, 1.0M solution in heptane
• Solubility Information: Solubility in water: vigorous reaction. Other solubilities: miscible with saturated aliphatic and aromatic, hydrocarbons
• Formula Weight: 142.22
• Packaging: AcroSeal™ Glass Bottle
• Specific Gravity: 0.7
• Quantity: 800 mL
• Flash Point: −1°C
• Physical Form: Solution

Safety and Handling

Product Identifier

• Diisobutylaluminium hydride, 1.0M solution in heptane

Signal Word

• Danger

Hazard Category

• LONG-TERM AQUATIC HAZARD Chronic 2
• Aspiration toxicity Category 1
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 A
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H304-May be fatal if swallowed and enters airways.
• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H411-Toxic to aquatic life with long lasting effects.
• H336-May cause drowsiness or dizziness.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P231+P232-Handle under inert gas. Protect from moisture.
• P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
• P273-Avoid release to the environment.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P302+P334-IF ON SKIN: Immerse in cool water/wrap in wet bandages.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.
• P335+P334-Brush off loose particles from skin Immerse in cool water/wrap in wet bandages.
• P402+P404-Store in a dry place. Store in a closed container.

SDS

RUO – Research Use Only