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Pyranodioxins

Organic bicyclic compounds that consist of a pyran ring fused to a dioxin ring.

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1

Thermo Scientific Chemicals 4,6-O-Ethylidene-D-glucopyranose, 90%

CAS: 13224-99-2 Molecular Formula: C8H14O6 Molecular Weight (g/mol): 206.19 MDL Number: MFCD00006820 InChI Key: VZPBLPQAMPVTFO-UHFFFAOYNA-N Synonym: 4,6-o-ethylidene-a-d-glucose PubChem CID: 21581900 IUPAC Name: (2R,4aR,6S,7R,8R,8aS)-2-methyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxine-6,7,8-triol SMILES: CC1OCC2OC(O)C(O)C(O)C2O1

PubChem CID 21581900
CAS 13224-99-2
Molecular Weight (g/mol) 206.19
MDL Number MFCD00006820
SMILES CC1OCC2OC(O)C(O)C(O)C2O1
Synonym 4,6-o-ethylidene-a-d-glucose
IUPAC Name (2R,4aR,6S,7R,8R,8aS)-2-methyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxine-6,7,8-triol
InChI Key VZPBLPQAMPVTFO-UHFFFAOYNA-N
Molecular Formula C8H14O6
2

Methyl 4,6-O-benzylidene-alpha-D-glucopyranoside, 97%

CAS: 3162-96-7 Molecular Formula: C14H18O6 Molecular Weight (g/mol): 282.292 MDL Number: MFCD00006819 InChI Key: VVSWDMJYIDBTMV-BTZLDLHRSA-N Synonym: 4ar,6s,7r,8r,8as-6-methoxy-2-phenylhexahydropyrano 3,2-d 1,3 dioxine-7,8-diol,methyl 4,6-o-benzylidene-alpha-d-glucopyranoside,methyl 4,6-o-benzylidene-a-d-glucopyranoside,4ar,6s,7r,8r,8as-6-methoxy-2-phenyl-hexahydro-2h-pyrano 3,2-d 1,3 dioxine-7,8-diol,methyl 4,6-o-benzylidenehexopyranoside #,zlchem 511,methyl 4,6-o-benzylidene-,a-d-glucopyranoside,methyl 4,6-o-phenylmethylene-,glucopyranoside, methyl 4,6-o-benzylidene-, .alpha.-d,.alpha.-d-glucopyranoside, methyl 4,6-o-phenylmethylene PubChem CID: 11822086 IUPAC Name: (4aR,6S,7R,8R,8aS)-6-methoxy-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxine-7,8-diol SMILES: COC1C(C(C2C(O1)COC(O2)C3=CC=CC=C3)O)O

PubChem CID 11822086
CAS 3162-96-7
Molecular Weight (g/mol) 282.292
MDL Number MFCD00006819
SMILES COC1C(C(C2C(O1)COC(O2)C3=CC=CC=C3)O)O
Synonym 4ar,6s,7r,8r,8as-6-methoxy-2-phenylhexahydropyrano 3,2-d 1,3 dioxine-7,8-diol,methyl 4,6-o-benzylidene-alpha-d-glucopyranoside,methyl 4,6-o-benzylidene-a-d-glucopyranoside,4ar,6s,7r,8r,8as-6-methoxy-2-phenyl-hexahydro-2h-pyrano 3,2-d 1,3 dioxine-7,8-diol,methyl 4,6-o-benzylidenehexopyranoside #,zlchem 511,methyl 4,6-o-benzylidene-,a-d-glucopyranoside,methyl 4,6-o-phenylmethylene-,glucopyranoside, methyl 4,6-o-benzylidene-, .alpha.-d,.alpha.-d-glucopyranoside, methyl 4,6-o-phenylmethylene
IUPAC Name (4aR,6S,7R,8R,8aS)-6-methoxy-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxine-7,8-diol
InChI Key VVSWDMJYIDBTMV-BTZLDLHRSA-N
Molecular Formula C14H18O6
3

4,6-O-Isopropylidene-D-glucal, 97%, Thermo Scientific Chemicals

CAS: 51450-36-3 Molecular Formula: C9H14O4 Molecular Weight (g/mol): 186.207 MDL Number: MFCD22988998 InChI Key: GAQDIYMHBQNXLE-PRJMDXOYSA-N Synonym: 4,6-o-isopropylidene-d-glucal,4-o,6-o-isopropylidene-1,2-dideoxy-d-arabino-1-hexenopyranose,1,2-didehydro-1,2-dideoxy-4-o,6-o-isopropylidene-beta-d-glucopyranose,4ar,8r,8as-2,2-dimethyl-4h,4ah,8h,8ah-pyrano 3,2-d 1,3 dioxin-8-ol PubChem CID: 11052343 IUPAC Name: (4aR,8R,8aS)-2,2-dimethyl-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-8-ol SMILES: CC1(OCC2C(O1)C(C=CO2)O)C

PubChem CID 11052343
CAS 51450-36-3
Molecular Weight (g/mol) 186.207
MDL Number MFCD22988998
SMILES CC1(OCC2C(O1)C(C=CO2)O)C
Synonym 4,6-o-isopropylidene-d-glucal,4-o,6-o-isopropylidene-1,2-dideoxy-d-arabino-1-hexenopyranose,1,2-didehydro-1,2-dideoxy-4-o,6-o-isopropylidene-beta-d-glucopyranose,4ar,8r,8as-2,2-dimethyl-4h,4ah,8h,8ah-pyrano 3,2-d 1,3 dioxin-8-ol
IUPAC Name (4aR,8R,8aS)-2,2-dimethyl-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-8-ol
InChI Key GAQDIYMHBQNXLE-PRJMDXOYSA-N
Molecular Formula C9H14O4
4

4,6-O-Benzylidene-D-glucal, 97%, Thermo Scientific Chemicals

CAS: 14125-70-3 Molecular Formula: C13H14O4 Molecular Weight (g/mol): 234.25 MDL Number: MFCD00167506 InChI Key: XMDUTBYCCVWPLD-FVCCEPFGSA-N Synonym: 4,6-o-benzylidene-d-glucal,2s,4ar,8r,8as-2-phenyl-4,4a,8,8a-tetrahydropyrano 3,2-d 1,3 dioxin-8-ol PubChem CID: 7067543 IUPAC Name: (2S,4aR,8R,8aS)-2-phenyl-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-8-ol SMILES: O[C@@H]1C=CO[C@@H]2CO[C@H](O[C@@H]12)C1=CC=CC=C1

PubChem CID 7067543
CAS 14125-70-3
Molecular Weight (g/mol) 234.25
MDL Number MFCD00167506
SMILES O[C@@H]1C=CO[C@@H]2CO[C@H](O[C@@H]12)C1=CC=CC=C1
Synonym 4,6-o-benzylidene-d-glucal,2s,4ar,8r,8as-2-phenyl-4,4a,8,8a-tetrahydropyrano 3,2-d 1,3 dioxin-8-ol
IUPAC Name (2S,4aR,8R,8aS)-2-phenyl-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-8-ol
InChI Key XMDUTBYCCVWPLD-FVCCEPFGSA-N
Molecular Formula C13H14O4
5

2-([7-(acetylamino)-6-(benzyloxy)-2-phenylperhydropyrano[3,2-d][1,3]dioxin-8-yl]oxy)propanoic acid, Thermo Scientific™

CAS: 499104-69-7 Molecular Formula: C25H29NO8 Molecular Weight (g/mol): 471.506 InChI Key: JPPMVSNCFXDOJX-UHFFFAOYSA-N Synonym: 2-7-acetylamino-6-benzyloxy-2-phenylperhydropyrano 3,2-d 1,3 dioxin-8-yl oxy propanoic acid,2r-2-4ar,6s,7r,8r,8as-7-acetamido-6-benzyloxy-2-phenylhexahydropyrano 3,2-d 1,3 dioxin-8-yl oxy propanoic acid,2-6-benzyloxy-7-acetamido-2-phenyl-hexahydro-2h-pyrano 3,2-d 1,3 dioxin-8-yl oxy propanoic acid,benzyl n-acetyl-4,6-o-benzylidenemuramic acid,2-7-acetamido-6-benzyloxy-2-phenylhexahydropyrano 3,2-d 1,3 dioxin-8-yl oxy propanoic acid,2-7-acetamido-2-phenyl-6-phenylmethoxy-4,4a,6,7,8,8a-hexahydropyrano 3,2-d 1,3 dioxin-8-yl oxy propanoic acid PubChem CID: 3843768 IUPAC Name: 2-[(7-acetamido-2-phenyl-6-phenylmethoxy-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-8-yl)oxy]propanoic acid SMILES: CC(C(=O)O)OC1C(C(OC2C1OC(OC2)C3=CC=CC=C3)OCC4=CC=CC=C4)NC(=O)C

PubChem CID 3843768
CAS 499104-69-7
Molecular Weight (g/mol) 471.506
SMILES CC(C(=O)O)OC1C(C(OC2C1OC(OC2)C3=CC=CC=C3)OCC4=CC=CC=C4)NC(=O)C
Synonym 2-7-acetylamino-6-benzyloxy-2-phenylperhydropyrano 3,2-d 1,3 dioxin-8-yl oxy propanoic acid,2r-2-4ar,6s,7r,8r,8as-7-acetamido-6-benzyloxy-2-phenylhexahydropyrano 3,2-d 1,3 dioxin-8-yl oxy propanoic acid,2-6-benzyloxy-7-acetamido-2-phenyl-hexahydro-2h-pyrano 3,2-d 1,3 dioxin-8-yl oxy propanoic acid,benzyl n-acetyl-4,6-o-benzylidenemuramic acid,2-7-acetamido-6-benzyloxy-2-phenylhexahydropyrano 3,2-d 1,3 dioxin-8-yl oxy propanoic acid,2-7-acetamido-2-phenyl-6-phenylmethoxy-4,4a,6,7,8,8a-hexahydropyrano 3,2-d 1,3 dioxin-8-yl oxy propanoic acid
IUPAC Name 2-[(7-acetamido-2-phenyl-6-phenylmethoxy-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-8-yl)oxy]propanoic acid
InChI Key JPPMVSNCFXDOJX-UHFFFAOYSA-N
Molecular Formula C25H29NO8
6

4-Nitrophenyl 2-Acetamido-4,6-O-methoxybenzylidene-2-deoxy-Alpha-D-galactopyranoside, TRC

CAS: 59868-86-9 Molecular Formula: C22 H24 N2 O9 Molecular Weight (g/mol): 460.43 IUPAC Name: N-[(4aR,6R,7R,8R,8aR)-8-hydroxy-2-(4-methoxyphenyl)-6-(4-nitrophenoxy)-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-7-yl]acetamide SMILES: COc1ccc(cc1)C2OC[C@H]3O[C@H](Oc4ccc(cc4)[N+](=O)[O-])[C@H](NC(=O)C)[C@@H](O)[C@H]3O2

CAS 59868-86-9
Molecular Weight (g/mol) 460.43
SMILES COc1ccc(cc1)C2OC[C@H]3O[C@H](Oc4ccc(cc4)[N+](=O)[O-])[C@H](NC(=O)C)[C@@H](O)[C@H]3O2
IUPAC Name N-[(4aR,6R,7R,8R,8aR)-8-hydroxy-2-(4-methoxyphenyl)-6-(4-nitrophenoxy)-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-7-yl]acetamide
Molecular Formula C22 H24 N2 O9
7

4,6-O-(4-Methoxybenzylidene)-D-glucal, 97%, Thermo Scientific™

CAS: 312623-79-3 Molecular Formula: C14H16O5 Molecular Weight (g/mol): 264.277 MDL Number: MFCD01863528 InChI Key: SSKZQXMNNREVNP-HABKJSAYSA-N Synonym: 4,6-o-4-methoxybenzylidene-d-glucal,4 6-o-4-methoxybenzylidene-d-glucal,4-o,6-o-4-methoxybenzylidene-1,2-dideoxy-d-arabino-1-hexenopyranose,1,5-anhydro-4-o,6-o-4-methoxybenzylidene-2-deoxy-d-arabino-hexa-1-enitol,4ar,8r,8as-2-4-methoxyphenyl-2h,4h,4ah,8h,8ah-pyrano 3,2-d 1,3 dioxin-8-ol PubChem CID: 46185760 IUPAC Name: (4aR,8R,8aS)-2-(4-methoxyphenyl)-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-8-ol SMILES: COC1=CC=C(C=C1)C2OCC3C(O2)C(C=CO3)O

PubChem CID 46185760
CAS 312623-79-3
Molecular Weight (g/mol) 264.277
MDL Number MFCD01863528
SMILES COC1=CC=C(C=C1)C2OCC3C(O2)C(C=CO3)O
Synonym 4,6-o-4-methoxybenzylidene-d-glucal,4 6-o-4-methoxybenzylidene-d-glucal,4-o,6-o-4-methoxybenzylidene-1,2-dideoxy-d-arabino-1-hexenopyranose,1,5-anhydro-4-o,6-o-4-methoxybenzylidene-2-deoxy-d-arabino-hexa-1-enitol,4ar,8r,8as-2-4-methoxyphenyl-2h,4h,4ah,8h,8ah-pyrano 3,2-d 1,3 dioxin-8-ol
IUPAC Name (4aR,8R,8aS)-2-(4-methoxyphenyl)-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-8-ol
InChI Key SSKZQXMNNREVNP-HABKJSAYSA-N
Molecular Formula C14H16O5
8

3-O-Benzoyl-4,6-O-isopropylidene-D-glucal, 97%, Thermo Scientific™

CAS: 58871-20-8 Molecular Formula: C16H18O5 Molecular Weight (g/mol): 290.32 MDL Number: MFCD22988992 InChI Key: RADJUQJHMUFUJI-UHFFFAOYNA-N Synonym: 3-o-benzoyl-4,6-o-isopropylidene-d-glucal,4ar,8r,8as-2,2-dimethyl-4h,4ah,8h,8ah-pyrano 3,2-d 1,3 dioxin-8-yl benzoate PubChem CID: 92135621 IUPAC Name: [(4aR,8R,8aS)-2,2-dimethyl-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-8-yl] benzoate SMILES: CC1(C)OCC2OC=CC(OC(=O)C3=CC=CC=C3)C2O1

PubChem CID 92135621
CAS 58871-20-8
Molecular Weight (g/mol) 290.32
MDL Number MFCD22988992
SMILES CC1(C)OCC2OC=CC(OC(=O)C3=CC=CC=C3)C2O1
Synonym 3-o-benzoyl-4,6-o-isopropylidene-d-glucal,4ar,8r,8as-2,2-dimethyl-4h,4ah,8h,8ah-pyrano 3,2-d 1,3 dioxin-8-yl benzoate
IUPAC Name [(4aR,8R,8aS)-2,2-dimethyl-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-8-yl] benzoate
InChI Key RADJUQJHMUFUJI-UHFFFAOYNA-N
Molecular Formula C16H18O5
9

3-O-tert-Butyldimethylsilyl-4,6-O-(4-methoxybenzylidene)-D-glucal, 97%, Thermo Scientific™

CAS: 384346-91-2 Molecular Formula: C20H30O5Si Molecular Weight (g/mol): 378.54 MDL Number: MFCD01863523 InChI Key: ZTRSSQRWGPRALW-UHFFFAOYNA-N Synonym: 3-o-tert-butyldimethylsilyl-4,6-o-4-methoxybenzylidene-d-glucal,4ar,8r,8ar-2-4-methoxyphenyl-2h,4h,4ah,8h,8ah-pyrano 3,2-d 1,3 dioxin-8-yl oxy tert-butyl dimethylsilane PubChem CID: 71311532 SMILES: COC1=CC=C(C=C1)C1OCC2OC=CC(O[Si](C)(C)C(C)(C)C)C2O1

PubChem CID 71311532
CAS 384346-91-2
Molecular Weight (g/mol) 378.54
MDL Number MFCD01863523
SMILES COC1=CC=C(C=C1)C1OCC2OC=CC(O[Si](C)(C)C(C)(C)C)C2O1
Synonym 3-o-tert-butyldimethylsilyl-4,6-o-4-methoxybenzylidene-d-glucal,4ar,8r,8ar-2-4-methoxyphenyl-2h,4h,4ah,8h,8ah-pyrano 3,2-d 1,3 dioxin-8-yl oxy tert-butyl dimethylsilane
InChI Key ZTRSSQRWGPRALW-UHFFFAOYNA-N
Molecular Formula C20H30O5Si
10

Benzyl 2-acetamido-4,6-O-benzylidene-2-deoxy-alpha-D-glucopyranoside, Thermo Scientific™

CAS: 13343-63-0 Molecular Formula: C22H25NO6 Molecular Weight (g/mol): 399.443 MDL Number: MFCD00143679 InChI Key: NXGXFAKJUWEFEC-NVZUTRPHSA-N Synonym: n-4ar,6s,7r,8r,8as-6-benzyloxy-8-hydroxy-2-phenylhexahydropyrano 3,2-d 1,3 dioxin-7-yl acetamide,benzyl-2-acetamido-4,6-o-benzylidene-2-deoxy-alpha-d-glcopyranoside,benzyl 2-acetamido-4,6-o-benzylidene-2-deoxy-alpha-d-glucopyranoside,n-4ar,6s,7r,8r,8as-6-benzyloxy-8-hydroxy-2-phenyl-hexahydro-2h-pyrano 3,2-d 1,3 dioxin-7-yl acetamide,maybridge1_006454,benzyl 2-acetamido-4,6-o-benzylidene-2-deoxy-,a-d-glucopyranoside,phenylmethyl 2-acetylamino-2-deoxy-4,6-o-phenylmethylene-,1-o-benzyl-n-acetyl-4-o,6-o-benzylidene-alpha-d-glucosamine,benzyl 2-acetamido-4,6-o-benzylidene-2-deoxy-a-d-glcopyranoside,benzyl-2-acetamido-4,6-o-benzylidene-2-deoxy- PubChem CID: 2735220 IUPAC Name: N-[(4aR,6S,7R,8R,8aS)-8-hydroxy-2-phenyl-6-phenylmethoxy-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-7-yl]acetamide SMILES: CC(=O)NC1C(C2C(COC(O2)C3=CC=CC=C3)OC1OCC4=CC=CC=C4)O

PubChem CID 2735220
CAS 13343-63-0
Molecular Weight (g/mol) 399.443
MDL Number MFCD00143679
SMILES CC(=O)NC1C(C2C(COC(O2)C3=CC=CC=C3)OC1OCC4=CC=CC=C4)O
Synonym n-4ar,6s,7r,8r,8as-6-benzyloxy-8-hydroxy-2-phenylhexahydropyrano 3,2-d 1,3 dioxin-7-yl acetamide,benzyl-2-acetamido-4,6-o-benzylidene-2-deoxy-alpha-d-glcopyranoside,benzyl 2-acetamido-4,6-o-benzylidene-2-deoxy-alpha-d-glucopyranoside,n-4ar,6s,7r,8r,8as-6-benzyloxy-8-hydroxy-2-phenyl-hexahydro-2h-pyrano 3,2-d 1,3 dioxin-7-yl acetamide,maybridge1_006454,benzyl 2-acetamido-4,6-o-benzylidene-2-deoxy-,a-d-glucopyranoside,phenylmethyl 2-acetylamino-2-deoxy-4,6-o-phenylmethylene-,1-o-benzyl-n-acetyl-4-o,6-o-benzylidene-alpha-d-glucosamine,benzyl 2-acetamido-4,6-o-benzylidene-2-deoxy-a-d-glcopyranoside,benzyl-2-acetamido-4,6-o-benzylidene-2-deoxy-
IUPAC Name N-[(4aR,6S,7R,8R,8aS)-8-hydroxy-2-phenyl-6-phenylmethoxy-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-7-yl]acetamide
InChI Key NXGXFAKJUWEFEC-NVZUTRPHSA-N
Molecular Formula C22H25NO6