Vinylmagnesium chloride, 1.7M (15 wt.%) solution in THF, AcroSeal®, ACROS Organics™

Brand:  Acros Organics 252598000

Product Code. 10043260

Chemical Identifiers

• CAS: 3536-96-7
• Molecular Weight (g/mol): 86.801
• InChI Key: IJMWREDHKRHWQI-UHFFFAOYSA-M
• PubChem CID: 77075
• SMILES: C=[CH-].[Mg+2].[Cl-]

• Molecular Formula: C2H3ClMg
• MDL Number: MFCD00013594
• Synonym: vinylmagnesium chloride, chlorovinylmagnesium, chloro ethenyl magnesium, vinyl magnesium chloride, magnesium, chloroethenyl, vinyl magnesium-chloride, vinyl-magnesium chloride, magnesium,chloroethenyl, ethenyl magnesium chloride, vinylmagnesium chloride solution
• IUPAC Name: magnesium;ethene;chloride

Specifications

• Chemical Name or Material: Vinylmagnesium chloride
• CAS: 109-99-9
• Linear Formula: CH₂=CHMgCl
• Density: 0.9800g/mL
• InChI Key: IJMWREDHKRHWQI-UHFFFAOYSA-M
• IUPAC Name: magnesium;ethene;chloride
• PubChem CID: 77075
• Physical Form: Crystalline Powder
• Packaging: AcroSeal™ Glass Bottle
• Specific Gravity: 0.98
• Boiling Point: 66.0°C
• Quantity: 800mL

• Name Note: 15 wt. % Solution in Tetrahydrofuran
• Molecular Formula: C2H3ClMg
• MDL Number: MFCD00013594
• Synonym: vinylmagnesium chloride, chlorovinylmagnesium, chloro ethenyl magnesium, vinyl magnesium chloride, magnesium, chloroethenyl, vinyl magnesium-chloride, vinyl-magnesium chloride, magnesium,chloroethenyl, ethenyl magnesium chloride, vinylmagnesium chloride solution
• SMILES: C=[CH-].[Mg+2].[Cl-]
• Molecular Weight (g/mol): 86.801
• Formula Weight: 86.8
• Percent Purity: 2M (18 wt.%)
• Solubility: Solubility in water: vigorous reaction.
• Storage Information: Below 10°C, crystallization of Grignard reagent will occur. Store between 10°C and 25°C.
• Color: White to Beige
• Flash Point: −017°C

Safety and Handling

Product Identifier

• Vinylmagnesium chloride, 1.9M (16.5 wt.%) solution in THF

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H351-Suspected of causing cancer.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H302-Harmful if swallowed.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P231+P232-Handle under inert gas. Protect from moisture.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.