Diethyl diallylmalonate, 97+%, Thermo Scientific Chemicals

Description

Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke?s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.

Solubility
Sparingly Soluble in water. (0.72 g/L) (25°C)

Notes
Store under cool dry place. Ensure good ventilation.

Specifications

• Density: 0.993
• Boiling Point: 242°C to 244°C
• Flash Point: >110°C (230°F)
• Refractive Index: 1.446
• Quantity: 10 g
• Beilstein: 1790529
• Synonym: diethyl diallylmalonate, diethyl 2,2-diallylmalonate, diallylmalonic acid diethyl ester, propanedioic acid, di-2-propenyl-, diethyl ester, 1,3-diethyl 2,2-bis prop-2-en-1-yl propanedioate, diethyl 2,2-diprop-2-enylpropane-1,3-dioate, diethyldiallylmalonate, malonic acid, diallyl-, diethyl ester, diethyl2,2-diallylmalonate, acmc-1cp69
• Solubility Information: Sparingly Soluble in water. (0.72g/L) (25°C)
• Formula Weight: 240.3
• Percent Purity: 98%
• Chemical Name or Material: Diethyl diallylmalonate

RUO – Research Use Only