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(Carbethoxymethylene)triphenylphosphorane, +98%, ACROS Organics™

£32.80 - £335.00

Chemical Identifiers

CAS 1099-45-2
Molecular Formula C22H21O2P
Molecular Weight (g/mol) 348.38
InChI Key IIHPVYJPDKJYOU-UHFFFAOYSA-N
Synonym carbethoxymethylene triphenylphosphorane, ethyl triphenylphosphoranylidene acetate, triphenylcarbethoxymethylenephosphorane, acetic acid, triphenylphosphoranylidene-, ethyl ester, ethyl 2-triphenylphosphoranylidene acetate, ethoxycarbonylmethylene triphenylphosphorane, carboethoxymethylidenetriphenylphosphorane, ethyl triphenylphosphoranilidene acetate, carbethoxytriphenylphosphonium methylide, carbethoxymethylidenetriphenylphosphorane
PubChem CID 70670
IUPAC Name ethyl 2-(triphenyl-$l^{5}-phosphanylidene)acetate
SMILES CCOC(=O)C=P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
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Products 3
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10496900 SDS View Documents Acros Organics
108290250
25g Glass bottle £32.80
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10020600 SDS View Documents Acros Organics
108291000
100g Glass bottle £93.70
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11955791 SDS View Documents Acros Organics
108295000
500g Glass bottle £335.00
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Estimated Shipment date
from Supplier 04-11-2019
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Description

Description

For C-C Bond Formation (Olefination)
Specifications

Chemical Identifiers

1099-45-2
348.38
carbethoxymethylene triphenylphosphorane, ethyl triphenylphosphoranylidene acetate, triphenylcarbethoxymethylenephosphorane, acetic acid, triphenylphosphoranylidene-, ethyl ester, ethyl 2-triphenylphosphoranylidene acetate, ethoxycarbonylmethylene triphenylphosphorane, carboethoxymethylidenetriphenylphosphorane, ethyl triphenylphosphoranilidene acetate, carbethoxytriphenylphosphonium methylide, carbethoxymethylidenetriphenylphosphorane
ethyl 2-(triphenyl-$l^{5}-phosphanylidene)acetate
C22H21O2P
IIHPVYJPDKJYOU-UHFFFAOYSA-N
70670
CCOC(=O)C=P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Specifications

25g
Authentic
White to Yellow
1099-45-2
100.0
C22H21O2P
01,112; 02,60; 10,78
Solubility in water: insoluble
CCOC(=O)C=P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
348.38
348.38
≥98%
(Carbethoxymethylene)triphenylphosphorane
Glass bottle
124.0°C to 129.0°C
98.0
98+%
(C6H5)3P=CHCO2C2H5
carbethoxymethylene triphenylphosphorane, ethyl triphenylphosphoranylidene acetate, triphenylcarbethoxymethylenephosphorane, acetic acid, triphenylphosphoranylidene-, ethyl ester, ethyl 2-triphenylphosphoranylidene acetate, ethoxycarbonylmethylene triphenylphosphorane, carboethoxymethylidenetriphenylphosphorane, ethyl triphenylphosphoranilidene acetate, carbethoxytriphenylphosphonium methylide, carbethoxymethylidenetriphenylphosphorane
IIHPVYJPDKJYOU-UHFFFAOYSA-N
ethyl 2-(triphenyl-$l^{5}-phosphanylidene)acetate
70670
Powder
Safety and Handling

Safety and Handling

Product Identifier
  • (Carbethoxymethylene)triphenylphosphorane

Signal Word
  • Danger

Hazard Category
  • Acute toxicity Category 3
  • Serious eye damage/eye irritation Category 2
  • Skin corrosion/irritation Category 2
  • Specific target organ toxicity Category 3

Hazard Statement
  • H315-Causes skin irritation.
  • H319-Causes serious eye irritation.
  • H335-May cause respiratory irritation.
  • H301-Toxic if swallowed.

Precautionary Statement
  • P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
  • P302+P352-IF ON SKIN: Wash with plenty of water/.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.